Atmospheric pressure chemical ionization studies of non-polar isomeric hydrocarbons using ion mobility spectrometry and mass spectrometry with different ionization techniques

The ionization pathways were determined for sets of isomeric non-polar hydrocarbons (structural isomers, cis/trans isomers) using ion mobility spectrometry and mass spectrometry with different techniques of atmospheric pressure chemical ionization to assess the influence of structural features on io...

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Published in:Journal of the American Society for Mass Spectrometry 2002-09, Vol.13 (9), p.1078-1087
Main Authors: Borsdorf, H, Nazarov, E.G, Eiceman, G.A
Format: Article
Language:English
Subjects:
Abundance
Analytical chemistry
Atmospheric Pressure
Chemistry
Cyclohexanes - analysis
Cyclopentanes - analysis
Discharge
Environmental Monitoring - methods
Exact sciences and technology
Hydrocarbons
Hydrocarbons - analysis
Hydrocarbons, Cyclic - analysis
Ionic mobility
Ionization
Ions
Isomerism
Isomers
Life Sciences (General)
Mass spectrometry
Mass Spectrometry - methods
Nickel
Photoionization
Radioisotopes
Scientific imaging
Spacecraft
Spectrometric and optical methods
Spectroscopy
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description The ionization pathways were determined for sets of isomeric non-polar hydrocarbons (structural isomers, cis/trans isomers) using ion mobility spectrometry and mass spectrometry with different techniques of atmospheric pressure chemical ionization to assess the influence of structural features on ion formation. Depending on the structural features, different ions were observed using mass spectrometry. Unsaturated hydrocarbons formed mostly [M − 1] + and [(M − 1) 2H] + ions while mainly [M − 3] + and [(M − 3)H 2O] + ions were found for saturated cis/trans isomers using photoionization and 63Ni ionization. These ionization methods and corona discharge ionization were used for ion mobility measurements of these compounds. Different ions were detected for compounds with different structural features. 63Ni ionization and photoionization provide comparable ions for every set of isomers. The product ions formed can be clearly attributed to the structures identified. However, differences in relative abundance of product ions were found. Although corona discharge ionization permits the most sensitive detection of non-polar hydrocarbons, the spectra detected are complex and differ from those obtained with 63Ni ionization and photoionization.
doi_str_mv 10.1016/S1044-0305(02)00429-4
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identifier ISSN: 1044-0305
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Abundance
Analytical chemistry
Atmospheric Pressure
Chemistry
Cyclohexanes - analysis
Cyclopentanes - analysis
Discharge
Environmental Monitoring - methods
Exact sciences and technology
Hydrocarbons
Hydrocarbons - analysis
Hydrocarbons, Cyclic - analysis
Ionic mobility
Ionization
Ions
Isomerism
Isomers
Life Sciences (General)
Mass spectrometry
Mass Spectrometry - methods
Nickel
Photoionization
Radioisotopes
Scientific imaging
Spacecraft
Spectrometric and optical methods
Spectroscopy
title Atmospheric pressure chemical ionization studies of non-polar isomeric hydrocarbons using ion mobility spectrometry and mass spectrometry with different ionization techniques
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