Reversible Small‐Molecule Interactions with Coordinatively Unsaturated Metal Centers Held in Metallathiaborane Clusters

The metallathiaboranes [8,8‐(dppe)‐nido‐8,7‐NiSB9H11] [1, dppe = bis(diphenylphosphanyl)ethane], [7‐Et‐8,8‐(dppe)‐nido‐8,7‐NiSB9H10] (2), [9‐Et‐8,8‐(dppe)‐nido‐8,7‐NiSB9H10] (3) and [2,2‐(dppe)‐closo‐2,1‐NiSB8H8] (4) are isolated from the reactions between Cs[arachno‐SB9H12], Li[BHEt3] and [NiCl2(dp...

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Bibliographic Details
Published in:European journal of inorganic chemistry 2017-10, Vol.2017 (38-39), p.4599-4617
Main Authors: Bould, Jonathan, Passarelli, Vincenzo, Oro, Luis A., Macías, Ramón
Format: Article
Language:English
Subjects:
Ammonia
Boranes
Cluster compounds
Coordination compounds
Ethane
Infrared spectroscopy
Inorganic chemistry
Iridium
Metallaboranes
Nickel
NMR
NMR spectroscopy
Nuclear magnetic resonance
Shielding
Single crystals
Spectrum analysis
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Summary:The metallathiaboranes [8,8‐(dppe)‐nido‐8,7‐NiSB9H11] [1, dppe = bis(diphenylphosphanyl)ethane], [7‐Et‐8,8‐(dppe)‐nido‐8,7‐NiSB9H10] (2), [9‐Et‐8,8‐(dppe)‐nido‐8,7‐NiSB9H10] (3) and [2,2‐(dppe)‐closo‐2,1‐NiSB8H8] (4) are isolated from the reactions between Cs[arachno‐SB9H12], Li[BHEt3] and [NiCl2(dppe)] at low temperature in yields of 30, 1, 0.1 and
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.201700539