Effect of metalation-demetalation reactions on the assembly and properties of 2D supramolecular arrays of tetrapyridylporphyrin and its Zn(II)-complex

[Display omitted] •Porphyrin-based coordination networks were assembled in Langmuir monolayers.•Metalation/demetalation reactions were monitored by fiber-optic spectroscopy.•Mechanism of porphyrin metalation varies in solution and thin film at the interface.•Solid-immobilized films of coordination 2...

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Bibliographic Details
Published in:Surface science 2017-06, Vol.660, p.39-46
Main Authors: Ermakova, Elizaveta V., Meshkov, Ivan N., Yu. Enakieva, Yuliya, Zvyagina, Alexandra I., Ezhov, Alexander A., Mikhaylov, Alexey A., Gorbunova, Yuliya G., Chernyshev, Vladimir V., Kalinina, Maria A., Arslanov, Vladimir V.
Format: Article
Language:English
Subjects:
Chemical reactions
Coordination compounds
Coordination polymers
Fluorescence
Ligands
Metal-organic frameworks
Optical properties
Polymers
Porphyrins
Spectrum analysis
Studies
Substrates
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Summary:[Display omitted] •Porphyrin-based coordination networks were assembled in Langmuir monolayers.•Metalation/demetalation reactions were monitored by fiber-optic spectroscopy.•Mechanism of porphyrin metalation varies in solution and thin film at the interface.•Solid-immobilized films of coordination 2D network were obtained and studied.
ISSN:0039-6028
1879-2758
DOI:10.1016/j.susc.2017.02.007