Understanding the effect of postsynthesis ammonium treatment on the catalytic activity of Au/Ti-SBA-15 catalysts for the oxidation of propene

• Published in: Journal of catalysis 2008-10, Vol.259 (1), p.43-53
• Main Authors: Sacaliuc-Parvulescu, Elena, Friedrich, Heiner, Palkovits, Regina, Weckhuysen, Bert M., Nijhuis, T. Alexander
• Format: Article
• Language: English
• Subjects: Catalysis; Catalysts; Chemistry; Colloidal state and disperse state; Comparative studies; Exact sciences and technology; General and physical chemistry; Gold; Hydrogen; Oxygen; Physical and chemical studies. Granulometry. Electrokinetic phenomena; Porous materials; Postsynthesis treatment; Propene epoxidation; SBA-15; Surface physical chemistry; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
• ISSN: 0021-9517; 1090-2694
• DOI: 10.1016/j.jcat.2008.07.013

Postsynthesis ammonium treatment induces a substantial increase in the catalytic activity of Au/Ti-SBA-15 catalysts for the direct vapor-phase epoxidation of propylene using hydrogen and oxygen. The PO formation rate of a calcined Au/Ti-SBA-15 catalyst prepared by this method increased from 4.3 mg PO h −1 g −1 cat to 37.2 mg PO h −1 g −1 cat at 200 °C compared with a catalyst prepared in an identical manner without this treatment. The catalysts were characterized by XRD, N 2-sorption, UV–vis–NIR DRS, 29Si MAS NMR, FT-IR spectroscopy, and TEM to gain insight into the relationship between ammonia treatment and catalyst activity. 29Si MAS NMR measurements proved that the ammonium nitrate solution caused hydrolysis of Si O Si or Ti O Si bonds, resulting in a Ti-SBA-15 surface with a greater amount of surface hydroxyl groups. FT-IR measurements indicated the presence of amine species that favor the homogeneous deposition of Au nanoparticles. This was confirmed by TEM measurements showing greater metal dispersion for NH 4NO 3-treated Au/Ti-SBA-15 materials.