Good sulfur tolerance of a mesoporous Beta zeolite-supported palladium catalyst in the deep hydrogenation of aromatics

• Published in: Journal of catalysis 2008-07, Vol.257 (1), p.125-133
• Main Authors: Tang, Tiandi, Yin, Chengyang, Wang, Lifeng, Ji, Yanyan, Xiao, Feng-Shou
• Format: Article
• Language: English
• Subjects: 4,6-Dimethyldibenzothiophene; Acids; Catalysis; Catalysts; Chemistry; Colloidal state and disperse state; Exact sciences and technology; General and physical chemistry; Hydrodesulfurization; Hydrogenation; Ion-exchange; Mesoporous Beta zeolite; Naphthalene; Palladium catalyst; Porous materials; Pyrene; Ratios; Sulfur; Sulfur tolerance; Surface physical chemistry; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Zeolites: preparations and properties
• ISSN: 0021-9517; 1090-2694
• DOI: 10.1016/j.jcat.2008.04.013

The activities of a Pd catalyst supported on mesoporous Beta zeolite (Beta-H) were evaluated for the hydrogenation of naphthalene and pyrene in the absence and presence of 200-ppm sulfur and for the hydrodesulfurization (HDS) of 4,6-dimethyldibenzothiophene (4,6-DMDBT). Compared with Pd/Al-MCM-41, the Pd/Beta-H catalyst exhibited better sulfur tolerance for hydrogenation of naphthalene and pyrene and higher activity for HDS of 4,6-DMDBT. The ratio of the hydrogenation of the second ring naphthalene in the absence and presence of 200-ppm sulfur for Pd/Beta-H was larger than that for Pd/Al-MCM-41 (0.47 vs 0.19). The desulfurization effect of Pd/Beta-H was greater than that of Pd/Al-MCM-41 (51 vs 35%). The difference in sulfur tolerance and HDS ability of the 2 catalysts is attributed to the difference in support acidity. Beta-H exhibited more acidic sites and a higher percentage of strong acidic sites than Al-MCM-41 (552 μmol/g and 43% vs 291 μmol/g and 18%).