Highly active Co–B amorphous alloy catalyst with uniform nanoparticles prepared in oil-in-water microemulsion

• Published in: Journal of catalysis 2008-10, Vol.259 (1), p.104-110
• Main Authors: Li, Hui, Liu, Jun, Xie, Songhai, Qiao, Minghua, Dai, Weilin, Li, Hexing
• Format: Article
• Language: English
• Subjects: Catalysis; Catalysts; Chemical synthesis; Chemistry; Cinnamaldehyde; Cinnamyl alcohol; Colloidal state and disperse state; Co–B amorphous alloy catalyst; Electron microscopes; Emulsions. Microemulsions. Foams; Exact sciences and technology; General and physical chemistry; Hydrogenation; Microemulsion; Nanoparticles; Physical and chemical studies. Granulometry. Electrokinetic phenomena; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Uniform diameter
• ISSN: 0021-9517; 1090-2694
• DOI: 10.1016/j.jcat.2008.07.015

Uniform Co–B nanoparticles were synthesized for the first time by chemical reduction of cobalt ion with borohydride in an oil-in-water microemulsion system comprising cyclohexane, polyethylene glycol, and water. The particle size was controlled by modulating the cyclohexane content. With the characterization of X-ray diffraction, selective area electronic diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy, the resulting Co–B nanoparticles were identified to be amorphous alloys ranging in size from 6 to 20 nm. During liquid-phase cinnamaldehyde hydrogenation, the as-synthesized Co–B catalyst was extremely active and more selective than the regular Co–B prepared in aqueous solution. Furthermore, this catalyst also was found to be more durable during the hydrogenation process.