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D-A Copolymers Based on a Pentacyclic Acceptor Unit and a 3,3′-Difluoro-2,2′-bithiophene for Solar Cells

A D-A copolymer, P2FBTTPTI, was developed by copolymerizing a pentacyclic acceptor unit, thieno[2′,3′:5,6]pyrido[3,4-g]thieno[3,2-c]isoquinoline-5,11(4 H,10 H)-dione(TPTI), with 3,3′-difluoro-2,2′-bithiophene(2 FBT). P2 FBTTPTI possessed a low highest occupied molecular orbital(HOMO) energy level(-5...

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Published in:Chinese journal of polymer science 2017-12, Vol.35 (12), p.1457-1462
Main Authors: Cao, Jia-min, Qian, Liu, He, Dan, Xiao, Zuo, Ding, Li-ming
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Language:English
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description A D-A copolymer, P2FBTTPTI, was developed by copolymerizing a pentacyclic acceptor unit, thieno[2′,3′:5,6]pyrido[3,4-g]thieno[3,2-c]isoquinoline-5,11(4 H,10 H)-dione(TPTI), with 3,3′-difluoro-2,2′-bithiophene(2 FBT). P2 FBTTPTI possessed a low highest occupied molecular orbital(HOMO) energy level(-5.50 e V) and a good hole mobility(4.14 × 10^-4 cm^2·V^-1·s^-1). P2FBTTPTI:PC_(71)BM solar cells gave a decent power conversion efficiency(PCE) of 7.64% and a high open-circuit voltage(Voc) of 0.95 V.
doi_str_mv 10.1007/s10118-017-1996-4
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subjects Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Condensed Matter Physics
Copolymerization
Energy conversion efficiency
Hole mobility
HOMO
Industrial Chemistry/Chemical Engineering
Molecular orbitals
Open circuit voltage
Photovoltaic cells
Polymer Sciences
Solar cells
体单元
共聚物
分子轨道
功率转换效率
太阳能电池
开路电压
空穴迁移率
title D-A Copolymers Based on a Pentacyclic Acceptor Unit and a 3,3′-Difluoro-2,2′-bithiophene for Solar Cells
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