Loading…
Modeling of simultaneous extraction of uranyl nitrate and nitric acid by 36 vol.% tri-iso-amyl phosphate in n-dodecane
The simultaneous extraction of uranyl nitrate and nitric acid by 36 vol.% tri-iso-amyl phosphate (TiAP) in n-dodecane was experimentally studied and modeled. The batch extraction experiments were carried out at low concentration region of aqueous uranyl nitrate by 36 vol.% TiAP in n-dodecane at 25 °...
Saved in:
| Published in: | Journal of radioanalytical and nuclear chemistry 2017-11, Vol.314 (2), p.975-983 |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c355t-59912120778bbf6297ce6df5f7763121495b01d46bb8c927ea9f62a59750dbbc3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c355t-59912120778bbf6297ce6df5f7763121495b01d46bb8c927ea9f62a59750dbbc3 |
| container_end_page | 983 |
| container_issue | 2 |
| container_start_page | 975 |
| container_title | Journal of radioanalytical and nuclear chemistry |
| container_volume | 314 |
| creator | Balasubramonian, S. Sinha, Pranay Kumar Sivakumar, D. Mishra, Alok Kumar Sampath, M. Pandey, N. K. Kumar, Shekhar |
| description | The simultaneous extraction of uranyl nitrate and nitric acid by 36 vol.% tri-iso-amyl phosphate (TiAP) in n-dodecane was experimentally studied and modeled. The batch extraction experiments were carried out at low concentration region of aqueous uranyl nitrate by 36 vol.% TiAP in n-dodecane at 25 °C. The non idealities in aqueous phase were described by eNRTL model. The predicted organic phase concentration of nitric acid and uranyl nitrate obtained by considering the HNO
3
·TiAP and UO
2
(NO
3
)
2
·2TiAP species in the organic phase is in good agreement with the experimental data. |
| doi_str_mv | 10.1007/s10967-017-5474-9 |
| format | article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_1956100159</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A511784935</galeid><sourcerecordid>A511784935</sourcerecordid><originalsourceid>FETCH-LOGICAL-c355t-59912120778bbf6297ce6df5f7763121495b01d46bb8c927ea9f62a59750dbbc3</originalsourceid><addsrcrecordid>eNp1kc1OxCAUhYnRxHH0AdyRGJeM0JZSlpOJf4nGja4JUDrDpIURWnXexmfxyaTWhRvDAnLv-e4BDgDnBC8IxuwqEsxLhjBhiBasQPwAzAitKpSxCh-CGc7yElGWk2NwEuMWY8yrKp-B90dfm9a6NfQNjLYb2l4644cIzUcfpO6td2NrCNLtW-hsKvYGSlf_nK2GUtsaqj3My6_PN98uLmEqIxs9kl0idhsfd5uRsQ46VCc7nRxOwVEj22jOfvc5eLm5fl7doYen2_vV8gHpnNIeUc5JRjLMWKVUU2acaVPWDW0YK_PUKThVmNRFqVSlecaM5EklKWcU10rpfA4uprm74F8HE3ux9UNwyVIQTsv0d4TypFpMqrVsjbCu8ePb06pNZ7V3prGpvqSEsKrgOU0AmQAdfIzBNGIXbCfDXhAsxkDEFIhIgYgxEDGaZBMTk9atTfhzlX-hb7-7jnU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1956100159</pqid></control><display><type>article</type><title>Modeling of simultaneous extraction of uranyl nitrate and nitric acid by 36 vol.% tri-iso-amyl phosphate in n-dodecane</title><source>Springer Nature</source><creator>Balasubramonian, S. ; Sinha, Pranay Kumar ; Sivakumar, D. ; Mishra, Alok Kumar ; Sampath, M. ; Pandey, N. K. ; Kumar, Shekhar</creator><creatorcontrib>Balasubramonian, S. ; Sinha, Pranay Kumar ; Sivakumar, D. ; Mishra, Alok Kumar ; Sampath, M. ; Pandey, N. K. ; Kumar, Shekhar</creatorcontrib><description>The simultaneous extraction of uranyl nitrate and nitric acid by 36 vol.% tri-iso-amyl phosphate (TiAP) in n-dodecane was experimentally studied and modeled. The batch extraction experiments were carried out at low concentration region of aqueous uranyl nitrate by 36 vol.% TiAP in n-dodecane at 25 °C. The non idealities in aqueous phase were described by eNRTL model. The predicted organic phase concentration of nitric acid and uranyl nitrate obtained by considering the HNO
3
·TiAP and UO
2
(NO
3
)
2
·2TiAP species in the organic phase is in good agreement with the experimental data.</description><identifier>ISSN: 0236-5731</identifier><identifier>EISSN: 1588-2780</identifier><identifier>DOI: 10.1007/s10967-017-5474-9</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Analysis ; Chemistry ; Chemistry and Materials Science ; Diagnostic Radiology ; Dodecane ; Hadrons ; Heavy Ions ; Inorganic Chemistry ; Nitrates ; Nitric acid ; Nuclear Chemistry ; Nuclear energy ; Nuclear industry ; Nuclear Physics ; Phosphates ; Physical Chemistry ; Spent reactor fuels ; Uranium ; Uranium compounds</subject><ispartof>Journal of radioanalytical and nuclear chemistry, 2017-11, Vol.314 (2), p.975-983</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2017</rights><rights>COPYRIGHT 2017 Springer</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c355t-59912120778bbf6297ce6df5f7763121495b01d46bb8c927ea9f62a59750dbbc3</citedby><cites>FETCH-LOGICAL-c355t-59912120778bbf6297ce6df5f7763121495b01d46bb8c927ea9f62a59750dbbc3</cites><orcidid>0000-0003-1577-8846</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Balasubramonian, S.</creatorcontrib><creatorcontrib>Sinha, Pranay Kumar</creatorcontrib><creatorcontrib>Sivakumar, D.</creatorcontrib><creatorcontrib>Mishra, Alok Kumar</creatorcontrib><creatorcontrib>Sampath, M.</creatorcontrib><creatorcontrib>Pandey, N. K.</creatorcontrib><creatorcontrib>Kumar, Shekhar</creatorcontrib><title>Modeling of simultaneous extraction of uranyl nitrate and nitric acid by 36 vol.% tri-iso-amyl phosphate in n-dodecane</title><title>Journal of radioanalytical and nuclear chemistry</title><addtitle>J Radioanal Nucl Chem</addtitle><description>The simultaneous extraction of uranyl nitrate and nitric acid by 36 vol.% tri-iso-amyl phosphate (TiAP) in n-dodecane was experimentally studied and modeled. The batch extraction experiments were carried out at low concentration region of aqueous uranyl nitrate by 36 vol.% TiAP in n-dodecane at 25 °C. The non idealities in aqueous phase were described by eNRTL model. The predicted organic phase concentration of nitric acid and uranyl nitrate obtained by considering the HNO
3
·TiAP and UO
2
(NO
3
)
2
·2TiAP species in the organic phase is in good agreement with the experimental data.</description><subject>Analysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Diagnostic Radiology</subject><subject>Dodecane</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Inorganic Chemistry</subject><subject>Nitrates</subject><subject>Nitric acid</subject><subject>Nuclear Chemistry</subject><subject>Nuclear energy</subject><subject>Nuclear industry</subject><subject>Nuclear Physics</subject><subject>Phosphates</subject><subject>Physical Chemistry</subject><subject>Spent reactor fuels</subject><subject>Uranium</subject><subject>Uranium compounds</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kc1OxCAUhYnRxHH0AdyRGJeM0JZSlpOJf4nGja4JUDrDpIURWnXexmfxyaTWhRvDAnLv-e4BDgDnBC8IxuwqEsxLhjBhiBasQPwAzAitKpSxCh-CGc7yElGWk2NwEuMWY8yrKp-B90dfm9a6NfQNjLYb2l4644cIzUcfpO6td2NrCNLtW-hsKvYGSlf_nK2GUtsaqj3My6_PN98uLmEqIxs9kl0idhsfd5uRsQ46VCc7nRxOwVEj22jOfvc5eLm5fl7doYen2_vV8gHpnNIeUc5JRjLMWKVUU2acaVPWDW0YK_PUKThVmNRFqVSlecaM5EklKWcU10rpfA4uprm74F8HE3ux9UNwyVIQTsv0d4TypFpMqrVsjbCu8ePb06pNZ7V3prGpvqSEsKrgOU0AmQAdfIzBNGIXbCfDXhAsxkDEFIhIgYgxEDGaZBMTk9atTfhzlX-hb7-7jnU</recordid><startdate>20171101</startdate><enddate>20171101</enddate><creator>Balasubramonian, S.</creator><creator>Sinha, Pranay Kumar</creator><creator>Sivakumar, D.</creator><creator>Mishra, Alok Kumar</creator><creator>Sampath, M.</creator><creator>Pandey, N. K.</creator><creator>Kumar, Shekhar</creator><general>Springer Netherlands</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-1577-8846</orcidid></search><sort><creationdate>20171101</creationdate><title>Modeling of simultaneous extraction of uranyl nitrate and nitric acid by 36 vol.% tri-iso-amyl phosphate in n-dodecane</title><author>Balasubramonian, S. ; Sinha, Pranay Kumar ; Sivakumar, D. ; Mishra, Alok Kumar ; Sampath, M. ; Pandey, N. K. ; Kumar, Shekhar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c355t-59912120778bbf6297ce6df5f7763121495b01d46bb8c927ea9f62a59750dbbc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Analysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Diagnostic Radiology</topic><topic>Dodecane</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Inorganic Chemistry</topic><topic>Nitrates</topic><topic>Nitric acid</topic><topic>Nuclear Chemistry</topic><topic>Nuclear energy</topic><topic>Nuclear industry</topic><topic>Nuclear Physics</topic><topic>Phosphates</topic><topic>Physical Chemistry</topic><topic>Spent reactor fuels</topic><topic>Uranium</topic><topic>Uranium compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Balasubramonian, S.</creatorcontrib><creatorcontrib>Sinha, Pranay Kumar</creatorcontrib><creatorcontrib>Sivakumar, D.</creatorcontrib><creatorcontrib>Mishra, Alok Kumar</creatorcontrib><creatorcontrib>Sampath, M.</creatorcontrib><creatorcontrib>Pandey, N. K.</creatorcontrib><creatorcontrib>Kumar, Shekhar</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Balasubramonian, S.</au><au>Sinha, Pranay Kumar</au><au>Sivakumar, D.</au><au>Mishra, Alok Kumar</au><au>Sampath, M.</au><au>Pandey, N. K.</au><au>Kumar, Shekhar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Modeling of simultaneous extraction of uranyl nitrate and nitric acid by 36 vol.% tri-iso-amyl phosphate in n-dodecane</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2017-11-01</date><risdate>2017</risdate><volume>314</volume><issue>2</issue><spage>975</spage><epage>983</epage><pages>975-983</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>The simultaneous extraction of uranyl nitrate and nitric acid by 36 vol.% tri-iso-amyl phosphate (TiAP) in n-dodecane was experimentally studied and modeled. The batch extraction experiments were carried out at low concentration region of aqueous uranyl nitrate by 36 vol.% TiAP in n-dodecane at 25 °C. The non idealities in aqueous phase were described by eNRTL model. The predicted organic phase concentration of nitric acid and uranyl nitrate obtained by considering the HNO
3
·TiAP and UO
2
(NO
3
)
2
·2TiAP species in the organic phase is in good agreement with the experimental data.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10967-017-5474-9</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-1577-8846</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0236-5731 |
| ispartof | Journal of radioanalytical and nuclear chemistry, 2017-11, Vol.314 (2), p.975-983 |
| issn | 0236-5731 1588-2780 |
| language | eng |
| recordid | cdi_proquest_journals_1956100159 |
| source | Springer Nature |
| subjects | Analysis Chemistry Chemistry and Materials Science Diagnostic Radiology Dodecane Hadrons Heavy Ions Inorganic Chemistry Nitrates Nitric acid Nuclear Chemistry Nuclear energy Nuclear industry Nuclear Physics Phosphates Physical Chemistry Spent reactor fuels Uranium Uranium compounds |
| title | Modeling of simultaneous extraction of uranyl nitrate and nitric acid by 36 vol.% tri-iso-amyl phosphate in n-dodecane |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T18%3A51%3A31IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Modeling%20of%20simultaneous%20extraction%20of%20uranyl%20nitrate%20and%20nitric%20acid%20by%2036%C2%A0vol.%25%20tri-iso-amyl%20phosphate%20in%20n-dodecane&rft.jtitle=Journal%20of%20radioanalytical%20and%20nuclear%20chemistry&rft.au=Balasubramonian,%20S.&rft.date=2017-11-01&rft.volume=314&rft.issue=2&rft.spage=975&rft.epage=983&rft.pages=975-983&rft.issn=0236-5731&rft.eissn=1588-2780&rft_id=info:doi/10.1007/s10967-017-5474-9&rft_dat=%3Cgale_proqu%3EA511784935%3C/gale_proqu%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c355t-59912120778bbf6297ce6df5f7763121495b01d46bb8c927ea9f62a59750dbbc3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1956100159&rft_id=info:pmid/&rft_galeid=A511784935&rfr_iscdi=true |