Loading…
Palladium-free and phosphine-free Sonogashira coupling reaction of aryl halides with terminal alkynes catalyzed by boehmite nanoparticle-anchored Cu(I) diethylenetriamine complex
In this work, a novel diethylenetriamine-functionalized-boehmite nanoparticle-supported Cu(I) catalyst is synthesized. The catalyst prepared is then characterized by FT-IR spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction spectroscopy, and inductively co...
Saved in:
Published in: | Research on chemical intermediates 2017-12, Vol.43 (12), p.7347-7363 |
---|---|
Main Authors: | , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-c316t-8cee9fb7833849af5efa2bdbe69e30e2604cfe56ad95c2eaeb45aa4ed87fd61d3 |
---|---|
cites | cdi_FETCH-LOGICAL-c316t-8cee9fb7833849af5efa2bdbe69e30e2604cfe56ad95c2eaeb45aa4ed87fd61d3 |
container_end_page | 7363 |
container_issue | 12 |
container_start_page | 7347 |
container_title | Research on chemical intermediates |
container_volume | 43 |
creator | Bakherad, Mohammad Doosti, Rahele Mirzaee, Mahdi Jadidi, Khosrow Amin, Amir H. Amiri, Omid |
description | In this work, a novel diethylenetriamine-functionalized-boehmite nanoparticle-supported Cu(I) catalyst is synthesized. The catalyst prepared is then characterized by FT-IR spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction spectroscopy, and inductively coupled plasma techniques. The catalyst prepared shows great activity in the Sonogashira coupling reaction of aryl halides with terminal alkynes in DMF under an argon atmosphere. Moreover, it could be removed from the reaction mixture by means of simple filtration and used again for up to six runs without an appreciable loss in its activity. |
doi_str_mv | 10.1007/s11164-017-3079-0 |
format | article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1959995451</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1959995451</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-8cee9fb7833849af5efa2bdbe69e30e2604cfe56ad95c2eaeb45aa4ed87fd61d3</originalsourceid><addsrcrecordid>eNp1kcGK1jAUhYso-Dv6AO4CbnQRTdombZby4-jAgIK6LrfJ7d-MaVKTFK2P5ROaoS7cuLpwOOdc7v2q6jlnrzlj3ZvEOZctZbyjDesUZQ-qExeyp0J24mF1YqquqeSyf1w9SemOMS76np2q35_AOTB2W-gUEQl4Q9Y5pHW2Hg_pc_DhAmm2EYgO2-qsv5CIoLMNnoSJQNwdmcFZg4n8sHkmGeNiPTgC7tvui6ohg9t_oSHjTsaA82IzEg8-rBCz1Q4peD2HWBzn7eXNK2Is5nl36DFHC6UNy_JldfjzafVoApfw2d95VX29fvfl_IHefnx_c357S3XDZaa9RlTT2PVN07cKJoET1KMZUSpsGNaStXpCIcEooWsEHFsB0KLpu8lIbpqr6sXRu8bwfcOUh7uwxXJVGrgSSinRCl5c_HDpGFKKOA1rtEt5ycDZcI9mONAMBc1wj2ZgJVMfmVS8_oLxn-b_hv4AK2CX2g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1959995451</pqid></control><display><type>article</type><title>Palladium-free and phosphine-free Sonogashira coupling reaction of aryl halides with terminal alkynes catalyzed by boehmite nanoparticle-anchored Cu(I) diethylenetriamine complex</title><source>Springer Nature</source><creator>Bakherad, Mohammad ; Doosti, Rahele ; Mirzaee, Mahdi ; Jadidi, Khosrow ; Amin, Amir H. ; Amiri, Omid</creator><creatorcontrib>Bakherad, Mohammad ; Doosti, Rahele ; Mirzaee, Mahdi ; Jadidi, Khosrow ; Amin, Amir H. ; Amiri, Omid</creatorcontrib><description>In this work, a novel diethylenetriamine-functionalized-boehmite nanoparticle-supported Cu(I) catalyst is synthesized. The catalyst prepared is then characterized by FT-IR spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction spectroscopy, and inductively coupled plasma techniques. The catalyst prepared shows great activity in the Sonogashira coupling reaction of aryl halides with terminal alkynes in DMF under an argon atmosphere. Moreover, it could be removed from the reaction mixture by means of simple filtration and used again for up to six runs without an appreciable loss in its activity.</description><identifier>ISSN: 0922-6168</identifier><identifier>EISSN: 1568-5675</identifier><identifier>DOI: 10.1007/s11164-017-3079-0</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Alkynes ; Aromatic compounds ; Boehmite ; Catalysis ; Catalysts ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Coupling ; Electron microscopes ; Fourier transforms ; Halides ; Inductively coupled plasma ; Infrared spectroscopy ; Inorganic Chemistry ; Nanoparticles ; Palladium ; Physical Chemistry ; Scanning electron microscopy ; Spectrum analysis</subject><ispartof>Research on chemical intermediates, 2017-12, Vol.43 (12), p.7347-7363</ispartof><rights>Springer Science+Business Media B.V. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-8cee9fb7833849af5efa2bdbe69e30e2604cfe56ad95c2eaeb45aa4ed87fd61d3</citedby><cites>FETCH-LOGICAL-c316t-8cee9fb7833849af5efa2bdbe69e30e2604cfe56ad95c2eaeb45aa4ed87fd61d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Bakherad, Mohammad</creatorcontrib><creatorcontrib>Doosti, Rahele</creatorcontrib><creatorcontrib>Mirzaee, Mahdi</creatorcontrib><creatorcontrib>Jadidi, Khosrow</creatorcontrib><creatorcontrib>Amin, Amir H.</creatorcontrib><creatorcontrib>Amiri, Omid</creatorcontrib><title>Palladium-free and phosphine-free Sonogashira coupling reaction of aryl halides with terminal alkynes catalyzed by boehmite nanoparticle-anchored Cu(I) diethylenetriamine complex</title><title>Research on chemical intermediates</title><addtitle>Res Chem Intermed</addtitle><description>In this work, a novel diethylenetriamine-functionalized-boehmite nanoparticle-supported Cu(I) catalyst is synthesized. The catalyst prepared is then characterized by FT-IR spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction spectroscopy, and inductively coupled plasma techniques. The catalyst prepared shows great activity in the Sonogashira coupling reaction of aryl halides with terminal alkynes in DMF under an argon atmosphere. Moreover, it could be removed from the reaction mixture by means of simple filtration and used again for up to six runs without an appreciable loss in its activity.</description><subject>Alkynes</subject><subject>Aromatic compounds</subject><subject>Boehmite</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coupling</subject><subject>Electron microscopes</subject><subject>Fourier transforms</subject><subject>Halides</subject><subject>Inductively coupled plasma</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Nanoparticles</subject><subject>Palladium</subject><subject>Physical Chemistry</subject><subject>Scanning electron microscopy</subject><subject>Spectrum analysis</subject><issn>0922-6168</issn><issn>1568-5675</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kcGK1jAUhYso-Dv6AO4CbnQRTdombZby4-jAgIK6LrfJ7d-MaVKTFK2P5ROaoS7cuLpwOOdc7v2q6jlnrzlj3ZvEOZctZbyjDesUZQ-qExeyp0J24mF1YqquqeSyf1w9SemOMS76np2q35_AOTB2W-gUEQl4Q9Y5pHW2Hg_pc_DhAmm2EYgO2-qsv5CIoLMNnoSJQNwdmcFZg4n8sHkmGeNiPTgC7tvui6ohg9t_oSHjTsaA82IzEg8-rBCz1Q4peD2HWBzn7eXNK2Is5nl36DFHC6UNy_JldfjzafVoApfw2d95VX29fvfl_IHefnx_c357S3XDZaa9RlTT2PVN07cKJoET1KMZUSpsGNaStXpCIcEooWsEHFsB0KLpu8lIbpqr6sXRu8bwfcOUh7uwxXJVGrgSSinRCl5c_HDpGFKKOA1rtEt5ycDZcI9mONAMBc1wj2ZgJVMfmVS8_oLxn-b_hv4AK2CX2g</recordid><startdate>20171201</startdate><enddate>20171201</enddate><creator>Bakherad, Mohammad</creator><creator>Doosti, Rahele</creator><creator>Mirzaee, Mahdi</creator><creator>Jadidi, Khosrow</creator><creator>Amin, Amir H.</creator><creator>Amiri, Omid</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20171201</creationdate><title>Palladium-free and phosphine-free Sonogashira coupling reaction of aryl halides with terminal alkynes catalyzed by boehmite nanoparticle-anchored Cu(I) diethylenetriamine complex</title><author>Bakherad, Mohammad ; Doosti, Rahele ; Mirzaee, Mahdi ; Jadidi, Khosrow ; Amin, Amir H. ; Amiri, Omid</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-8cee9fb7833849af5efa2bdbe69e30e2604cfe56ad95c2eaeb45aa4ed87fd61d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Alkynes</topic><topic>Aromatic compounds</topic><topic>Boehmite</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coupling</topic><topic>Electron microscopes</topic><topic>Fourier transforms</topic><topic>Halides</topic><topic>Inductively coupled plasma</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Nanoparticles</topic><topic>Palladium</topic><topic>Physical Chemistry</topic><topic>Scanning electron microscopy</topic><topic>Spectrum analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bakherad, Mohammad</creatorcontrib><creatorcontrib>Doosti, Rahele</creatorcontrib><creatorcontrib>Mirzaee, Mahdi</creatorcontrib><creatorcontrib>Jadidi, Khosrow</creatorcontrib><creatorcontrib>Amin, Amir H.</creatorcontrib><creatorcontrib>Amiri, Omid</creatorcontrib><collection>CrossRef</collection><jtitle>Research on chemical intermediates</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bakherad, Mohammad</au><au>Doosti, Rahele</au><au>Mirzaee, Mahdi</au><au>Jadidi, Khosrow</au><au>Amin, Amir H.</au><au>Amiri, Omid</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Palladium-free and phosphine-free Sonogashira coupling reaction of aryl halides with terminal alkynes catalyzed by boehmite nanoparticle-anchored Cu(I) diethylenetriamine complex</atitle><jtitle>Research on chemical intermediates</jtitle><stitle>Res Chem Intermed</stitle><date>2017-12-01</date><risdate>2017</risdate><volume>43</volume><issue>12</issue><spage>7347</spage><epage>7363</epage><pages>7347-7363</pages><issn>0922-6168</issn><eissn>1568-5675</eissn><abstract>In this work, a novel diethylenetriamine-functionalized-boehmite nanoparticle-supported Cu(I) catalyst is synthesized. The catalyst prepared is then characterized by FT-IR spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction spectroscopy, and inductively coupled plasma techniques. The catalyst prepared shows great activity in the Sonogashira coupling reaction of aryl halides with terminal alkynes in DMF under an argon atmosphere. Moreover, it could be removed from the reaction mixture by means of simple filtration and used again for up to six runs without an appreciable loss in its activity.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11164-017-3079-0</doi><tpages>17</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0922-6168 |
ispartof | Research on chemical intermediates, 2017-12, Vol.43 (12), p.7347-7363 |
issn | 0922-6168 1568-5675 |
language | eng |
recordid | cdi_proquest_journals_1959995451 |
source | Springer Nature |
subjects | Alkynes Aromatic compounds Boehmite Catalysis Catalysts Chemical synthesis Chemistry Chemistry and Materials Science Coupling Electron microscopes Fourier transforms Halides Inductively coupled plasma Infrared spectroscopy Inorganic Chemistry Nanoparticles Palladium Physical Chemistry Scanning electron microscopy Spectrum analysis |
title | Palladium-free and phosphine-free Sonogashira coupling reaction of aryl halides with terminal alkynes catalyzed by boehmite nanoparticle-anchored Cu(I) diethylenetriamine complex |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T18%3A12%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Palladium-free%20and%20phosphine-free%20Sonogashira%20coupling%20reaction%20of%20aryl%20halides%20with%20terminal%20alkynes%20catalyzed%20by%20boehmite%20nanoparticle-anchored%20Cu(I)%20diethylenetriamine%20complex&rft.jtitle=Research%20on%20chemical%20intermediates&rft.au=Bakherad,%20Mohammad&rft.date=2017-12-01&rft.volume=43&rft.issue=12&rft.spage=7347&rft.epage=7363&rft.pages=7347-7363&rft.issn=0922-6168&rft.eissn=1568-5675&rft_id=info:doi/10.1007/s11164-017-3079-0&rft_dat=%3Cproquest_cross%3E1959995451%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c316t-8cee9fb7833849af5efa2bdbe69e30e2604cfe56ad95c2eaeb45aa4ed87fd61d3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1959995451&rft_id=info:pmid/&rfr_iscdi=true |