Cover Feature: Solvent‐Induced Cadmium(II) Metal‐Organic Frameworks with Adjustable Guest‐Evacuated Porosity: Application in the Controllable Assembly of MOF‐Derived Porous Carbon Materials for Supercapacitors (Chem. Eur. J. 62/2017)

Five Cd‐MOFs, constructed from identical ligand ingredients under different solvents, were employed as precursors to prepare porous carbons (PCs) through a calcination process. The results reveal that the specific surface area of PCs is closely related to the porosity of Cd‐MOFs, and both could be a...

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Bibliographic Details
Published in:Chemistry : a European journal 2017-11, Vol.23 (62), p.15541-15541
Main Authors: Yue, Man‐Li, Jiang, Yi‐Fan, Zhang, Lin, Yu, Cheng‐Yan, Zou, Kang‐Yu, Li, Zuo‐Xi
Format: Article
Language:English
Subjects:
Cadmium
Capacitance
Cd-MOFs
chemical activation
Chemistry
Metal-organic frameworks
Porosity
porous carbon
Porous materials
solvent effects
Solvents
Supercapacitors
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Summary:Five Cd‐MOFs, constructed from identical ligand ingredients under different solvents, were employed as precursors to prepare porous carbons (PCs) through a calcination process. The results reveal that the specific surface area of PCs is closely related to the porosity of Cd‐MOFs, and both could be adjusted by the solvent. PCs were further activated by KOH to obtain APCs, and the APC‐dmf electrode exhibits the highest porosity, largest specific capacitance, and excellent cycling stability, which has a potential application in supercapacitors. More information can be found in the Full Paper by Z.‐X. Li et al. on page 15680.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201704084