Front Cover: Pd‐Catalyzed versus Uncatalyzed, PhI(OAc)2‐Mediated Cyclization Reactions of N6‐([1,1′‐Biaryl]‐2‐yl)Adenine Nucleosides (ChemCatChem 21/2017)

The Front Cover shows the beautifully delicate architecture of Hawa Mahal as a symbol of the delicate balance of various factors in the described C−N bond formation of N6‐([1,1′‐biaryl]‐2‐yl)adenine nucleosides promoted by PhI(OAc)2 under both Pd‐mediated and uncatalyzed reaction conditions, which u...

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Bibliographic Details
Published in:ChemCatChem 2017-11, Vol.9 (21), p.4014-4014
Main Authors: Satishkumar, Sakilam, Poudapally, Suresh, Vuram, Prasanna K., Gurram, Venkateshwarlu, Pottabathini, Narender, Sebastian, Dellamol, Yang, Lijia, Pradhan, Padmanava, Lakshman, Mahesh K.
Format: Article
Language:English
Subjects:
Aromatic compounds
benzimidazole
carbazole
Chemical reactions
cyclization
hypervalent iodine
Nucleosides
Palladium
Selectivity
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Summary:The Front Cover shows the beautifully delicate architecture of Hawa Mahal as a symbol of the delicate balance of various factors in the described C−N bond formation of N6‐([1,1′‐biaryl]‐2‐yl)adenine nucleosides promoted by PhI(OAc)2 under both Pd‐mediated and uncatalyzed reaction conditions, which ultimately leads to relatively complex product structures. In their Full Paper, S. Satishkumar et al. demonstrate that the selectivity of the reaction can be modulated to produce either carbazolyl or aryl benzimidazopurinyl nucleoside derivatives. More information can be found in the Full Paper by S. Satishkumar et al. on page 4058 in Issue 21, 2017 (DOI: 10.1002/cctc.201700918).
ISSN:1867-3880
1867-3899
DOI:10.1002/cctc.201701672