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Alternative binary blends and their synergistic effect on stability of soybean biodiesel
The primary antioxidant tert -butylhydroquinone (TBHQ) and an alternative additive, named 1,4-bis(ethylamino)-9,10-anthraquinone, were mixed to yield a potent blend able to be used in the field of biodiesel preservation. Physicochemical parameters such as peroxide value, total acid number, density a...
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Published in: | Clean technologies and environmental policy 2017-12, Vol.19 (10), p.2479-2489 |
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container_end_page | 2489 |
container_issue | 10 |
container_start_page | 2479 |
container_title | Clean technologies and environmental policy |
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creator | Roveda, Ana Carolina Tenório, Kátia Veronica Caires, Anderson Rodrigues Lima Ferreira, Valdir Souza de Carvalho, Cláudio Teodoro Trindade, Magno Aparecido Gonçalves |
description | The primary antioxidant
tert
-butylhydroquinone (TBHQ) and an alternative additive, named 1,4-bis(ethylamino)-9,10-anthraquinone, were mixed to yield a potent blend able to be used in the field of biodiesel preservation. Physicochemical parameters such as peroxide value, total acid number, density and induction period were used to evaluate the effectiveness of the combination in stabilising soybean biodiesel during the accelerate storage period of degradation. The induction period values were also used to calculate the occurrence of synergistic effect, and it was observed a high percentage of synergism for the combined additives. The results showed that the presence of target alternative additive also enables lower the concentration of the primary antioxidant (TBHQ) in the blend. The cost-effective comparison was evaluated, and it was verified that the final cost of biodiesel can also be lowered, since the amount of additives (in the blend) required to meet the biodiesel specifications was reduced between 70 and 88%. |
doi_str_mv | 10.1007/s10098-017-1445-7 |
format | article |
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tert
-butylhydroquinone (TBHQ) and an alternative additive, named 1,4-bis(ethylamino)-9,10-anthraquinone, were mixed to yield a potent blend able to be used in the field of biodiesel preservation. Physicochemical parameters such as peroxide value, total acid number, density and induction period were used to evaluate the effectiveness of the combination in stabilising soybean biodiesel during the accelerate storage period of degradation. The induction period values were also used to calculate the occurrence of synergistic effect, and it was observed a high percentage of synergism for the combined additives. The results showed that the presence of target alternative additive also enables lower the concentration of the primary antioxidant (TBHQ) in the blend. The cost-effective comparison was evaluated, and it was verified that the final cost of biodiesel can also be lowered, since the amount of additives (in the blend) required to meet the biodiesel specifications was reduced between 70 and 88%.</description><identifier>ISSN: 1618-954X</identifier><identifier>EISSN: 1618-9558</identifier><identifier>DOI: 10.1007/s10098-017-1445-7</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Additives ; Anthraquinone ; Antioxidants ; Biodiesel fuels ; Biofuels ; Clean technology ; Diesel ; Earth and Environmental Science ; Environment ; Environmental Economics ; Environmental Engineering/Biotechnology ; Environmental policy ; Industrial and Production Engineering ; Industrial Chemistry/Chemical Engineering ; Mixtures ; Original Paper ; Peroxide ; Physicochemical properties ; Preservation ; Soybeans ; Storage ; Sustainable Development ; Synergism ; Synergistic effect ; Yoga</subject><ispartof>Clean technologies and environmental policy, 2017-12, Vol.19 (10), p.2479-2489</ispartof><rights>Springer-Verlag GmbH Germany 2017</rights><rights>Clean Technologies and Environmental Policy is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-b62b5e6da47eb3f2f83f32931d803be03c8019d56e33c42242bae0a0479769b83</citedby><cites>FETCH-LOGICAL-c353t-b62b5e6da47eb3f2f83f32931d803be03c8019d56e33c42242bae0a0479769b83</cites><orcidid>0000-0003-4674-4809</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/1963842162/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/1963842162?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,11688,21394,27866,27924,27925,33611,36060,43733,44363,74221,74895</link.rule.ids></links><search><creatorcontrib>Roveda, Ana Carolina</creatorcontrib><creatorcontrib>Tenório, Kátia Veronica</creatorcontrib><creatorcontrib>Caires, Anderson Rodrigues Lima</creatorcontrib><creatorcontrib>Ferreira, Valdir Souza</creatorcontrib><creatorcontrib>de Carvalho, Cláudio Teodoro</creatorcontrib><creatorcontrib>Trindade, Magno Aparecido Gonçalves</creatorcontrib><title>Alternative binary blends and their synergistic effect on stability of soybean biodiesel</title><title>Clean technologies and environmental policy</title><addtitle>Clean Techn Environ Policy</addtitle><description>The primary antioxidant
tert
-butylhydroquinone (TBHQ) and an alternative additive, named 1,4-bis(ethylamino)-9,10-anthraquinone, were mixed to yield a potent blend able to be used in the field of biodiesel preservation. Physicochemical parameters such as peroxide value, total acid number, density and induction period were used to evaluate the effectiveness of the combination in stabilising soybean biodiesel during the accelerate storage period of degradation. The induction period values were also used to calculate the occurrence of synergistic effect, and it was observed a high percentage of synergism for the combined additives. The results showed that the presence of target alternative additive also enables lower the concentration of the primary antioxidant (TBHQ) in the blend. The cost-effective comparison was evaluated, and it was verified that the final cost of biodiesel can also be lowered, since the amount of additives (in the blend) required to meet the biodiesel specifications was reduced between 70 and 88%.</description><subject>Additives</subject><subject>Anthraquinone</subject><subject>Antioxidants</subject><subject>Biodiesel fuels</subject><subject>Biofuels</subject><subject>Clean technology</subject><subject>Diesel</subject><subject>Earth and Environmental Science</subject><subject>Environment</subject><subject>Environmental Economics</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Environmental policy</subject><subject>Industrial and Production Engineering</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Mixtures</subject><subject>Original Paper</subject><subject>Peroxide</subject><subject>Physicochemical properties</subject><subject>Preservation</subject><subject>Soybeans</subject><subject>Storage</subject><subject>Sustainable Development</subject><subject>Synergism</subject><subject>Synergistic effect</subject><subject>Yoga</subject><issn>1618-954X</issn><issn>1618-9558</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>7TQ</sourceid><sourceid>ALSLI</sourceid><sourceid>M0C</sourceid><sourceid>M2R</sourceid><recordid>eNp1kEtLAzEUhYMoWKs_wF3A9WheM8ksS_EFBTcK3YVk5qamjJmapML8e1Mq4sbNPXdxzoHzIXRNyS0lRN6lcltVESorKkRdyRM0ow1VVVvX6vT3F-tzdJHSlhDGJCMztF4MGWIw2X8Btj6YOGE7QOgTNqHH-R18xGkKEDc-Zd9hcA66jMeAUzbWDz5PeHQ4jZMFE0rF2HtIMFyiM2eGBFc_OkdvD_evy6dq9fL4vFysqo7XPFe2YbaGpjdCguWOOcUdZy2nvSLcAuGdIrTt6wY47wRjglkDxBAhW9m0VvE5ujn27uL4uYeU9Xbcl0FD0rRtuBKMNqy46NHVxTGlCE7vov8oYzUl-gBQHwHqAlAfAGpZMuyYScUbNhD_NP8b-gbLznOk</recordid><startdate>20171201</startdate><enddate>20171201</enddate><creator>Roveda, Ana 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binary blends and their synergistic effect on stability of soybean biodiesel</title><author>Roveda, Ana Carolina ; Tenório, Kátia Veronica ; Caires, Anderson Rodrigues Lima ; Ferreira, Valdir Souza ; de Carvalho, Cláudio Teodoro ; Trindade, Magno Aparecido Gonçalves</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-b62b5e6da47eb3f2f83f32931d803be03c8019d56e33c42242bae0a0479769b83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Additives</topic><topic>Anthraquinone</topic><topic>Antioxidants</topic><topic>Biodiesel fuels</topic><topic>Biofuels</topic><topic>Clean technology</topic><topic>Diesel</topic><topic>Earth and Environmental Science</topic><topic>Environment</topic><topic>Environmental Economics</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Environmental policy</topic><topic>Industrial and Production Engineering</topic><topic>Industrial 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policy</jtitle><stitle>Clean Techn Environ Policy</stitle><date>2017-12-01</date><risdate>2017</risdate><volume>19</volume><issue>10</issue><spage>2479</spage><epage>2489</epage><pages>2479-2489</pages><issn>1618-954X</issn><eissn>1618-9558</eissn><abstract>The primary antioxidant
tert
-butylhydroquinone (TBHQ) and an alternative additive, named 1,4-bis(ethylamino)-9,10-anthraquinone, were mixed to yield a potent blend able to be used in the field of biodiesel preservation. Physicochemical parameters such as peroxide value, total acid number, density and induction period were used to evaluate the effectiveness of the combination in stabilising soybean biodiesel during the accelerate storage period of degradation. The induction period values were also used to calculate the occurrence of synergistic effect, and it was observed a high percentage of synergism for the combined additives. The results showed that the presence of target alternative additive also enables lower the concentration of the primary antioxidant (TBHQ) in the blend. The cost-effective comparison was evaluated, and it was verified that the final cost of biodiesel can also be lowered, since the amount of additives (in the blend) required to meet the biodiesel specifications was reduced between 70 and 88%.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10098-017-1445-7</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0003-4674-4809</orcidid></addata></record> |
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subjects | Additives Anthraquinone Antioxidants Biodiesel fuels Biofuels Clean technology Diesel Earth and Environmental Science Environment Environmental Economics Environmental Engineering/Biotechnology Environmental policy Industrial and Production Engineering Industrial Chemistry/Chemical Engineering Mixtures Original Paper Peroxide Physicochemical properties Preservation Soybeans Storage Sustainable Development Synergism Synergistic effect Yoga |
title | Alternative binary blends and their synergistic effect on stability of soybean biodiesel |
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