Chlorobismuthates Trapping Dibromine: Formation of Two‐Dimensional Supramolecular Polyhalide Networks with Br2 Linkers

Reactions between BiCl3, Br2, and chlorides of pyridinium (1), 4,4′‐propylenedipyridinium (2), or trimethylphenylammonium (3) in aqueous HCl lead to the formation of chlorobismuthate complexes trapping {Br2} in the solid state into two‐dimensional polyhalide supramolecular networks. The nature of no...

Full description

Saved in:
Bibliographic Details
Published in:European journal of inorganic chemistry 2017-11, Vol.2017 (42), p.4925-4929
Main Authors: Adonin, Sergey A., Gorokh, Igor D., Abramov, Pavel A., Novikov, Alexander S., Korolkov, Ilya V., Sokolov, Maxim N., Fedin, Vladimir P.
Format: Article
Language:English
Subjects:
Density functional calculations
Halogens
Halometalates
Inorganic chemistry
Polyhalides
QTAIM
Trapping
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 4929
container_issue 42
container_start_page 4925
container_title European journal of inorganic chemistry
container_volume 2017
creator Adonin, Sergey A.
Gorokh, Igor D.
Abramov, Pavel A.
Novikov, Alexander S.
Korolkov, Ilya V.
Sokolov, Maxim N.
Fedin, Vladimir P.
description Reactions between BiCl3, Br2, and chlorides of pyridinium (1), 4,4′‐propylenedipyridinium (2), or trimethylphenylammonium (3) in aqueous HCl lead to the formation of chlorobismuthate complexes trapping {Br2} in the solid state into two‐dimensional polyhalide supramolecular networks. The nature of non‐covalent Br···Cl interactions was studied by theoretical methods; estimated energies of these interactions are 1.9–6.0 kcal/mol. Reactions between BiCl3, Br2, and chlorides of various organic cations in HCl result in formation of one‐ or two‐dimensional supramolecular networks built of chlorobismuthate and {Br2} units. The nature of non‐covalent Cl···Br interactions was studied by DFT calculations, which enabled the estimation of their energies (1.9–6.0 kcal/mol).
doi_str_mv 10.1002/ejic.201700908
format article
fullrecord <record><control><sourceid>proquest_wiley</sourceid><recordid>TN_cdi_proquest_journals_1964462841</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1964462841</sourcerecordid><originalsourceid>FETCH-LOGICAL-p1488-94c47916ba1cb014f22f31324f67b669f54e815216f92437261ae2139c23fe093</originalsourceid><addsrcrecordid>eNo9kMtOwzAQRSMEEqWwZW2JdYrHdp2YHfQBRRUgUdaRE2ziNomDnSh0xyfwjXwJqYq6unNHR6PRCYJLwCPAmFyrtclGBEOEscDxUTAALESIeUyO-5lRFoJg8Wlw5v0aY0wx5YPga5IX1tnU-LJtctkoj1ZO1rWpPtDUpM6WplI3aG5dKRtjK2Q1WnX29_tnakpV-X4lC_Ta1k6WtlBZW0iHXmyxzWVh3hV6Uk1n3cajzjQ5unMELU21Uc6fBydaFl5d_OcweJvPVpOHcPl8v5jcLsMaWByHgmUsEsBTCVmKgWlCNAVKmOZRyrnQY6ZiGBPgWhBGI8JBKgJUZIRqhQUdBlf7u7Wzn63yTbK2reuf9gkIzhgnMYOeEnuqM4XaJrUzpXTbBHCyU5vs1CYHtcnscTE5NPoHqsFxSQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1964462841</pqid></control><display><type>article</type><title>Chlorobismuthates Trapping Dibromine: Formation of Two‐Dimensional Supramolecular Polyhalide Networks with Br2 Linkers</title><source>Wiley</source><creator>Adonin, Sergey A. ; Gorokh, Igor D. ; Abramov, Pavel A. ; Novikov, Alexander S. ; Korolkov, Ilya V. ; Sokolov, Maxim N. ; Fedin, Vladimir P.</creator><creatorcontrib>Adonin, Sergey A. ; Gorokh, Igor D. ; Abramov, Pavel A. ; Novikov, Alexander S. ; Korolkov, Ilya V. ; Sokolov, Maxim N. ; Fedin, Vladimir P.</creatorcontrib><description>Reactions between BiCl3, Br2, and chlorides of pyridinium (1), 4,4′‐propylenedipyridinium (2), or trimethylphenylammonium (3) in aqueous HCl lead to the formation of chlorobismuthate complexes trapping {Br2} in the solid state into two‐dimensional polyhalide supramolecular networks. The nature of non‐covalent Br···Cl interactions was studied by theoretical methods; estimated energies of these interactions are 1.9–6.0 kcal/mol. Reactions between BiCl3, Br2, and chlorides of various organic cations in HCl result in formation of one‐ or two‐dimensional supramolecular networks built of chlorobismuthate and {Br2} units. The nature of non‐covalent Cl···Br interactions was studied by DFT calculations, which enabled the estimation of their energies (1.9–6.0 kcal/mol).</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.201700908</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Density functional calculations ; Halogens ; Halometalates ; Inorganic chemistry ; Polyhalides ; QTAIM ; Trapping</subject><ispartof>European journal of inorganic chemistry, 2017-11, Vol.2017 (42), p.4925-4929</ispartof><rights>2017 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><rights>2017 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-9889-5273</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Adonin, Sergey A.</creatorcontrib><creatorcontrib>Gorokh, Igor D.</creatorcontrib><creatorcontrib>Abramov, Pavel A.</creatorcontrib><creatorcontrib>Novikov, Alexander S.</creatorcontrib><creatorcontrib>Korolkov, Ilya V.</creatorcontrib><creatorcontrib>Sokolov, Maxim N.</creatorcontrib><creatorcontrib>Fedin, Vladimir P.</creatorcontrib><title>Chlorobismuthates Trapping Dibromine: Formation of Two‐Dimensional Supramolecular Polyhalide Networks with Br2 Linkers</title><title>European journal of inorganic chemistry</title><description>Reactions between BiCl3, Br2, and chlorides of pyridinium (1), 4,4′‐propylenedipyridinium (2), or trimethylphenylammonium (3) in aqueous HCl lead to the formation of chlorobismuthate complexes trapping {Br2} in the solid state into two‐dimensional polyhalide supramolecular networks. The nature of non‐covalent Br···Cl interactions was studied by theoretical methods; estimated energies of these interactions are 1.9–6.0 kcal/mol. Reactions between BiCl3, Br2, and chlorides of various organic cations in HCl result in formation of one‐ or two‐dimensional supramolecular networks built of chlorobismuthate and {Br2} units. The nature of non‐covalent Cl···Br interactions was studied by DFT calculations, which enabled the estimation of their energies (1.9–6.0 kcal/mol).</description><subject>Density functional calculations</subject><subject>Halogens</subject><subject>Halometalates</subject><subject>Inorganic chemistry</subject><subject>Polyhalides</subject><subject>QTAIM</subject><subject>Trapping</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNo9kMtOwzAQRSMEEqWwZW2JdYrHdp2YHfQBRRUgUdaRE2ziNomDnSh0xyfwjXwJqYq6unNHR6PRCYJLwCPAmFyrtclGBEOEscDxUTAALESIeUyO-5lRFoJg8Wlw5v0aY0wx5YPga5IX1tnU-LJtctkoj1ZO1rWpPtDUpM6WplI3aG5dKRtjK2Q1WnX29_tnakpV-X4lC_Ta1k6WtlBZW0iHXmyxzWVh3hV6Uk1n3cajzjQ5unMELU21Uc6fBydaFl5d_OcweJvPVpOHcPl8v5jcLsMaWByHgmUsEsBTCVmKgWlCNAVKmOZRyrnQY6ZiGBPgWhBGI8JBKgJUZIRqhQUdBlf7u7Wzn63yTbK2reuf9gkIzhgnMYOeEnuqM4XaJrUzpXTbBHCyU5vs1CYHtcnscTE5NPoHqsFxSQ</recordid><startdate>20171116</startdate><enddate>20171116</enddate><creator>Adonin, Sergey A.</creator><creator>Gorokh, Igor D.</creator><creator>Abramov, Pavel A.</creator><creator>Novikov, Alexander S.</creator><creator>Korolkov, Ilya V.</creator><creator>Sokolov, Maxim N.</creator><creator>Fedin, Vladimir P.</creator><general>Wiley Subscription Services, Inc</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-9889-5273</orcidid></search><sort><creationdate>20171116</creationdate><title>Chlorobismuthates Trapping Dibromine: Formation of Two‐Dimensional Supramolecular Polyhalide Networks with Br2 Linkers</title><author>Adonin, Sergey A. ; Gorokh, Igor D. ; Abramov, Pavel A. ; Novikov, Alexander S. ; Korolkov, Ilya V. ; Sokolov, Maxim N. ; Fedin, Vladimir P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p1488-94c47916ba1cb014f22f31324f67b669f54e815216f92437261ae2139c23fe093</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Density functional calculations</topic><topic>Halogens</topic><topic>Halometalates</topic><topic>Inorganic chemistry</topic><topic>Polyhalides</topic><topic>QTAIM</topic><topic>Trapping</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Adonin, Sergey A.</creatorcontrib><creatorcontrib>Gorokh, Igor D.</creatorcontrib><creatorcontrib>Abramov, Pavel A.</creatorcontrib><creatorcontrib>Novikov, Alexander S.</creatorcontrib><creatorcontrib>Korolkov, Ilya V.</creatorcontrib><creatorcontrib>Sokolov, Maxim N.</creatorcontrib><creatorcontrib>Fedin, Vladimir P.</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>European journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Adonin, Sergey A.</au><au>Gorokh, Igor D.</au><au>Abramov, Pavel A.</au><au>Novikov, Alexander S.</au><au>Korolkov, Ilya V.</au><au>Sokolov, Maxim N.</au><au>Fedin, Vladimir P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chlorobismuthates Trapping Dibromine: Formation of Two‐Dimensional Supramolecular Polyhalide Networks with Br2 Linkers</atitle><jtitle>European journal of inorganic chemistry</jtitle><date>2017-11-16</date><risdate>2017</risdate><volume>2017</volume><issue>42</issue><spage>4925</spage><epage>4929</epage><pages>4925-4929</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>Reactions between BiCl3, Br2, and chlorides of pyridinium (1), 4,4′‐propylenedipyridinium (2), or trimethylphenylammonium (3) in aqueous HCl lead to the formation of chlorobismuthate complexes trapping {Br2} in the solid state into two‐dimensional polyhalide supramolecular networks. The nature of non‐covalent Br···Cl interactions was studied by theoretical methods; estimated energies of these interactions are 1.9–6.0 kcal/mol. Reactions between BiCl3, Br2, and chlorides of various organic cations in HCl result in formation of one‐ or two‐dimensional supramolecular networks built of chlorobismuthate and {Br2} units. The nature of non‐covalent Cl···Br interactions was studied by DFT calculations, which enabled the estimation of their energies (1.9–6.0 kcal/mol).</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ejic.201700908</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-9889-5273</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1434-1948
ispartof European journal of inorganic chemistry, 2017-11, Vol.2017 (42), p.4925-4929
issn 1434-1948
1099-0682
language eng
recordid cdi_proquest_journals_1964462841
source Wiley
subjects Density functional calculations
Halogens
Halometalates
Inorganic chemistry
Polyhalides
QTAIM
Trapping
title Chlorobismuthates Trapping Dibromine: Formation of Two‐Dimensional Supramolecular Polyhalide Networks with Br2 Linkers
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T20%3A33%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_wiley&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Chlorobismuthates%20Trapping%20Dibromine:%20Formation%20of%20Two%E2%80%90Dimensional%20Supramolecular%20Polyhalide%20Networks%20with%20Br2%20Linkers&rft.jtitle=European%20journal%20of%20inorganic%20chemistry&rft.au=Adonin,%20Sergey%20A.&rft.date=2017-11-16&rft.volume=2017&rft.issue=42&rft.spage=4925&rft.epage=4929&rft.pages=4925-4929&rft.issn=1434-1948&rft.eissn=1099-0682&rft_id=info:doi/10.1002/ejic.201700908&rft_dat=%3Cproquest_wiley%3E1964462841%3C/proquest_wiley%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-p1488-94c47916ba1cb014f22f31324f67b669f54e815216f92437261ae2139c23fe093%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1964462841&rft_id=info:pmid/&rfr_iscdi=true