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An Effective Asphalt UV Blocking Material Based on Host-Guest Schiff Base/Layered Double Hydroxides

The development of asphalt-based UV blocking materials is important to extend the alphalt lifespan in road construction. In this work, we put forward that the fabrication of host-guest system can be an effective way to obtain UV blocking materials. Firstly, a new anionic Schiff base, N,N'bis(salicyl...

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Published in:Chinese journal of chemistry 2017-11, Vol.35 (11), p.1701-1705
Main Authors: Xia, Chunhui, Gao, Rui, Li, Kaitao, Yang, Yang, Lin, Yanjun, Yan, Dongpeng
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Language:English
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cited_by cdi_FETCH-LOGICAL-c3816-ac3e2a9699d9bb4e5a66519fdd3226a2e3f554dfa39a6220818fce7365667d4e3
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container_issue 11
container_start_page 1701
container_title Chinese journal of chemistry
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creator Xia, Chunhui
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Yan, Dongpeng
description The development of asphalt-based UV blocking materials is important to extend the alphalt lifespan in road construction. In this work, we put forward that the fabrication of host-guest system can be an effective way to obtain UV blocking materials. Firstly, a new anionic Schiff base, N,N'bis(salicylidine)-4,4'-diaminostilbene-2,2'-disulfonic acid (SDSD), has been synthesized, which was intercalated into Zn-Al-LDH by anion-exchange method. FT-IR and XRD illustrate the layered organic-inorganic composite, Zn-Al-SDSD-LDH, has been successfully synthesized with high crystallinity. Laser particle size analyzer, SEM and TEM show that particle size distributions of Zn-Al-SDSD-LDH is in the range 100--500 nm. UV-vis absorption spectra show that Zn-Al-SDSD-LDH has better UV absorption than the pristine Zn-Al-LDH and SDSD. Furthermore, the mixture of asphalt and 3 wt% Zn-Al-SDSD-LDH presents enhanced UV blocking property relative to the pristine asphalt after irradiating by UV spray accelerated weathering test. Therefore, this work not only develops a new type of host-guest Zn-Al-SDSD- LDH, but also confirms it can be an effective asphalt UV blocking material for practical application.
doi_str_mv 10.1002/cjoc.201700136
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source Wiley-Blackwell Read & Publish Collection
subjects Absorption
Absorption spectra
Accelerated tests
Aluminum
Anion exchanging
Asphalt
Composite materials
Fabrication
Host-guest materials
Hydroxides
Imines
layered double hydroxides
Life span
Particle size
Road construction
Schiff base
Synthesis
Ultraviolet radiation
UV blocking
Weathering
Zinc
title An Effective Asphalt UV Blocking Material Based on Host-Guest Schiff Base/Layered Double Hydroxides
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