Characterization and adsorption of disperse dyes from wastewater onto cenospheres activated carbon composites

• Published in: Environmental earth sciences 2017-10, Vol.76 (20), p.1-12, Article 702
• Main Authors: Markandeya, Shukla, S. P., Dhiman, N.
• Format: Article
• Language: English
• Subjects: Activated carbon; Adsorption; Biogeosciences; Capacity; Carbon; Cenospheres; Dyes; Earth and Environmental Science; Earth Sciences; Electric power generation; Electric power plants; Environmental Science and Engineering; Feasibility studies; Fly ash; Geochemistry; Geology; Hydrology/Water Resources; Original Article; pH effects; Pore size; Porosity; Power plants; Removal; Surface chemistry; Terrestrial Pollution; Thermal energy; Thermal power; Thermal power plants; Wastewater; Wastewater treatment
• ISSN: 1866-6280; 1866-6299
• DOI: 10.1007/s12665-017-7030-x

In the present research, coal fly ash, a waste by-product of thermal power plant, has been segregated to obtain hollow and spherical cenospheres which combined with activated carbon in different ratio for effectual remediation of wastewater. Fabricated cenospheres activated carbon (CNAC) composites were characterized by ATR-FTIR, SEM, XRD, BET and CILAS for functionality, surface modification, crystallinity, surface area, pore volume, pore size and particle size analysis, respectively. Batch adsorption has been applied to appraised maximum removal of Disperse Orange 25 (DO) and Disperse Blue 79:1 (DB) dyes at varying solution pH 2 to 12, adsorbent dose 0.1 g cenospheres + 0.1 g AC to 1.0 g cenospheres + 1.0 g AC, dye concentration 10 to 100 mg/L, agitation speed 80 to 240 rpm and contact time 5 to 300 min at three different temperatures (25, 35 and 45 °C). The maximum percentage removal was found to be 79 and 76% for DO and DB dyes, respectively, at optimized condition. Langmuir isotherm showed good interaction with adsorption data, and the obtained maximum equilibrium adsorption capacity was found to be 90.91 mg/g for DO and 83.33 mg/g for DB at 45 °C. Eventually, the negative ∆G° (− 7.513 for DO and − 7.767 for DB) has suggested the feasibility of dyes adsorption on CNAC composites.