Eco‐compatible three component strategies for C‐S bond formation in thioether and S‐aryl‐carbamodithioate compounds catalyzed by copper(II) nanoparticles supported on modified AlPO4

• Published in: Applied organometallic chemistry 2017-12, Vol.31 (12), p.n/a
• Main Authors: Sharghi, Hashem, Ghaderi, Iman, Doroodmand, Mohammad Mahdi
• Format: Article
• Language: English
• Subjects: Aluminum phosphate; Aromatic compounds; Bonding; Catalysis; Catalysts; Chemical reactions; Chemistry; Copper; Copper compounds; heterogeneous nanocatalyst; Leaching; S‐aryl‐carbamodithioates; thioethers; three component strategies; water; X ray photoelectron spectroscopy
• ISSN: 0268-2605; 1099-0739
• DOI: 10.1002/aoc.3869

One‐pot and three components C‐S bond formation reactions in thioethers and S‐aryl‐carbamodithioates have been catalyzed by a copper heterogeneous nano‐catalyst supported on modified AlPO4 under different reaction conditions. The above‐mentioned nano‐catalyst has been characterized by various techniques such as SEM, TEM, AFM, XRD, FT‐IR, UV–Vis, CV, BET, TGA, ICP and XPS spectrometry and its particle size was estimated to be between 60–110 nm. Finally, the reusability of the catalyst up to ten cycles without any significant leaching is one of the outstanding properties of the catalyst. Efficient, one‐pot and three components C‐S bond formation reactions in thioethers and S‐aryl‐carbamodithioates have been catalyzed by a copper heterogeneous nano‐catalyst supported on modified AlPO4 was developed. The nano‐catalyst has been characterized by SEM, TEM, AFM, XRD, FT‐IR, UV–Vis, CV, BET, TGA, ICP and XPS spectrometry.