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Synthesis, complexing properties, and selectivity of bis(diphenylphosphorylmethyl) ethers of oligoethylene glycols. Crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane
A convenient method of synthesis of phosphoryl-substituted podands with dipehnylphosphorylmethyl end groups of the general formula Ph 2 P(O)CH 2 O(CH 2 CH 2 O) n CH 2 P(O)Ph 2 ( L n , n = 0–6) is described. The stability constants of the complexes of the podands with alkali metal 2,4-dinitrophenolat...
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| Published in: | Russian journal of general chemistry 2017-11, Vol.87 (11), p.2574-2581 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c316t-93cac3ae5acf775cc012c3ca0d03ae1faf791a488bb3349492aa67a80814d4e93 |
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| cites | cdi_FETCH-LOGICAL-c316t-93cac3ae5acf775cc012c3ca0d03ae1faf791a488bb3349492aa67a80814d4e93 |
| container_end_page | 2581 |
| container_issue | 11 |
| container_start_page | 2574 |
| container_title | Russian journal of general chemistry |
| container_volume | 87 |
| creator | Ivanova, I. S. Baulin, V. E. Polyakova, I. N. Pyatova, E. N. Krivorot’ko, E. S. Galkina, E. N. Tsivadze, A. Yu |
| description | A convenient method of synthesis of phosphoryl-substituted podands with dipehnylphosphorylmethyl end groups of the general formula Ph
2
P(O)CH
2
O(CH
2
CH
2
O)
n
CH
2
P(O)Ph
2
(
L
n
,
n
= 0–6) is described. The stability constants of the complexes of the podands with alkali metal 2,4-dinitrophenolates were determined by conductometry. The ion-selective properties of the podands with respect to alkali and alkaline-earth metal cations were assessed by ionometry. The crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane was established by X-ray diffraction analysis. |
| doi_str_mv | 10.1134/S107036321711010X |
| format | article |
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2
P(O)CH
2
O(CH
2
CH
2
O)
n
CH
2
P(O)Ph
2
(
L
n
,
n
= 0–6) is described. The stability constants of the complexes of the podands with alkali metal 2,4-dinitrophenolates were determined by conductometry. The ion-selective properties of the podands with respect to alkali and alkaline-earth metal cations were assessed by ionometry. The crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane was established by X-ray diffraction analysis.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S107036321711010X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Alkali metals ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Crystal structure ; Ethers ; Ions ; Selectivity ; Stability constants ; Synthesis</subject><ispartof>Russian journal of general chemistry, 2017-11, Vol.87 (11), p.2574-2581</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-93cac3ae5acf775cc012c3ca0d03ae1faf791a488bb3349492aa67a80814d4e93</citedby><cites>FETCH-LOGICAL-c316t-93cac3ae5acf775cc012c3ca0d03ae1faf791a488bb3349492aa67a80814d4e93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Ivanova, I. S.</creatorcontrib><creatorcontrib>Baulin, V. E.</creatorcontrib><creatorcontrib>Polyakova, I. N.</creatorcontrib><creatorcontrib>Pyatova, E. N.</creatorcontrib><creatorcontrib>Krivorot’ko, E. S.</creatorcontrib><creatorcontrib>Galkina, E. N.</creatorcontrib><creatorcontrib>Tsivadze, A. Yu</creatorcontrib><title>Synthesis, complexing properties, and selectivity of bis(diphenylphosphorylmethyl) ethers of oligoethylene glycols. Crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>A convenient method of synthesis of phosphoryl-substituted podands with dipehnylphosphorylmethyl end groups of the general formula Ph
2
P(O)CH
2
O(CH
2
CH
2
O)
n
CH
2
P(O)Ph
2
(
L
n
,
n
= 0–6) is described. The stability constants of the complexes of the podands with alkali metal 2,4-dinitrophenolates were determined by conductometry. The ion-selective properties of the podands with respect to alkali and alkaline-earth metal cations were assessed by ionometry. The crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane was established by X-ray diffraction analysis.</description><subject>Alkali metals</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Crystal structure</subject><subject>Ethers</subject><subject>Ions</subject><subject>Selectivity</subject><subject>Stability constants</subject><subject>Synthesis</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kU1LxDAQhosouK7-AG8BLy5sNdN0-3GUxS9Y8LAK3ko2nW6zZJuapLL9Wf5DU9eDoB7ChHee952BCYJzoFcALL5eAk0pS1gEKQAF-noQjCChWcjYjB76v2-HQ_84OLF2Qz1Ck2gUfCz7xtVopZ0Sobetwp1s1qQ1ukXjJHqZNyWxqFA4-S5dT3RFVtJelrKtselVW2vrn-nVFl3dqwnxBY0dOK3kWn-p2CBZq15oZa_I3PTWcUWsM51wncGBhSkL_86dhFGod3zYiTd4GhxVXFk8-67j4OXu9nn-EC6e7h_nN4tQMEhcmDPBBeM446JK05kQFCLhNVpSr0LFqzQHHmfZasVYnMd5xHmS8oxmEJcx5mwcXOxz_dy3Dq0rNrozjR9ZQJ6mLJ7lNPEU7ClhtLUGq6I1cstNXwAthssUvy7jPdHeYz3brNH8SP7X9Ak_MZV8</recordid><startdate>20171101</startdate><enddate>20171101</enddate><creator>Ivanova, I. S.</creator><creator>Baulin, V. E.</creator><creator>Polyakova, I. N.</creator><creator>Pyatova, E. N.</creator><creator>Krivorot’ko, E. S.</creator><creator>Galkina, E. N.</creator><creator>Tsivadze, A. Yu</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20171101</creationdate><title>Synthesis, complexing properties, and selectivity of bis(diphenylphosphorylmethyl) ethers of oligoethylene glycols. Crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane</title><author>Ivanova, I. S. ; Baulin, V. E. ; Polyakova, I. N. ; Pyatova, E. N. ; Krivorot’ko, E. S. ; Galkina, E. N. ; Tsivadze, A. Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-93cac3ae5acf775cc012c3ca0d03ae1faf791a488bb3349492aa67a80814d4e93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Alkali metals</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Crystal structure</topic><topic>Ethers</topic><topic>Ions</topic><topic>Selectivity</topic><topic>Stability constants</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ivanova, I. S.</creatorcontrib><creatorcontrib>Baulin, V. E.</creatorcontrib><creatorcontrib>Polyakova, I. N.</creatorcontrib><creatorcontrib>Pyatova, E. N.</creatorcontrib><creatorcontrib>Krivorot’ko, E. S.</creatorcontrib><creatorcontrib>Galkina, E. N.</creatorcontrib><creatorcontrib>Tsivadze, A. Yu</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ivanova, I. S.</au><au>Baulin, V. E.</au><au>Polyakova, I. N.</au><au>Pyatova, E. N.</au><au>Krivorot’ko, E. S.</au><au>Galkina, E. N.</au><au>Tsivadze, A. Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, complexing properties, and selectivity of bis(diphenylphosphorylmethyl) ethers of oligoethylene glycols. Crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2017-11-01</date><risdate>2017</risdate><volume>87</volume><issue>11</issue><spage>2574</spage><epage>2581</epage><pages>2574-2581</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>A convenient method of synthesis of phosphoryl-substituted podands with dipehnylphosphorylmethyl end groups of the general formula Ph
2
P(O)CH
2
O(CH
2
CH
2
O)
n
CH
2
P(O)Ph
2
(
L
n
,
n
= 0–6) is described. The stability constants of the complexes of the podands with alkali metal 2,4-dinitrophenolates were determined by conductometry. The ion-selective properties of the podands with respect to alkali and alkaline-earth metal cations were assessed by ionometry. The crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane was established by X-ray diffraction analysis.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S107036321711010X</doi><tpages>8</tpages></addata></record> |
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| ispartof | Russian journal of general chemistry, 2017-11, Vol.87 (11), p.2574-2581 |
| issn | 1070-3632 1608-3350 |
| language | eng |
| recordid | cdi_proquest_journals_1977345906 |
| source | Springer Link |
| subjects | Alkali metals Chemistry Chemistry and Materials Science Chemistry/Food Science Crystal structure Ethers Ions Selectivity Stability constants Synthesis |
| title | Synthesis, complexing properties, and selectivity of bis(diphenylphosphorylmethyl) ethers of oligoethylene glycols. Crystal structure of 1,3-bis(diphenylphosphoryl)-2-oxapropane |
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