Synthesis of polyfluoralkylated 1,3,2-dioxaphospholane and 1,3,2-dioxaphosphorinane oxides

Polyfluoroalkyl dichlorophosphates easily react with 1,2- or 1,3-alkanediols in a system pyridine–diethyl ether and afford 2-polyfluoroalkoxy-1,3,2-dioxaphospholane oxides or 2-polyfluoroalkoxy-1,3,2-dioxaphosphorinane oxides. In similar conditions the reaction of methyl dichlorophosphate with 1,2-...

Full description

Saved in:
Bibliographic Details
Published in:Russian journal of organic chemistry 2017-11, Vol.53 (11), p.1623-1629
Main Authors: Gusarova, N. K., Verkhoturova, S. I., Arbuzova, S. N., Kazantseva, T. I., Albanov, A. I., Nalibaeva, A. M., Bishimbaeva, G. K.
Format: Article
Language:English
Subjects:
Alkanes
Chemistry
Chemistry and Materials Science
Diethyl ether
Organic Chemistry
Oxides
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Polyfluoroalkyl dichlorophosphates easily react with 1,2- or 1,3-alkanediols in a system pyridine–diethyl ether and afford 2-polyfluoroalkoxy-1,3,2-dioxaphospholane oxides or 2-polyfluoroalkoxy-1,3,2-dioxaphosphorinane oxides. In similar conditions the reaction of methyl dichlorophosphate with 1,2- and 1,3-alkanediols proceeds less effectively.
ISSN:1070-4280
1608-3393
DOI:10.1134/S107042801711001X