Structure of a gadolinium coordination compound with acyldihydrazone of adipic acid and 3-methyl-1-phenyl-4-formylpyrazol-5-one

The structure of a gadolinium coordination compound with acyldihydrazone of adipic acid and 3-methyl-1-phenyl-4-formylpyrazol-5-one is studied by the XRD. It is determined that the compound is built as a spacer-armed dinuclear complex in which coordination polyhedra are linked by three aliphatic bri...

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Bibliographic Details
Published in:Journal of structural chemistry 2017-12, Vol.58 (7), p.1464-1467
Main Authors: Shul′gin, V. F., Konnik, O. V., Bekirova, Z. Z., Aleksandrov, G. G., Kiskin, M. A., Eremenko, I. L.
Format: Article
Language:English
Subjects:
Aliphatic compounds
Atomic
Atomic/Molecular Structure and Spectra
Chemistry
Chemistry and Materials Science
Coordination compounds
Gadolinium
Inorganic Chemistry
Molecular
Nylon
Optical and Plasma Physics
Physical Chemistry
Polyhedra
Solid State Physics
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Summary:The structure of a gadolinium coordination compound with acyldihydrazone of adipic acid and 3-methyl-1-phenyl-4-formylpyrazol-5-one is studied by the XRD. It is determined that the compound is built as a spacer-armed dinuclear complex in which coordination polyhedra are linked by three aliphatic bridges packed in the asymmetric triple helix. The coordination polyhedron of the gadolinium cation has a slightly distorted three-capped trigonal prism geometry.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476617070290