Loading…
In situ analysis of the formation steps of gold nanoparticles by oleylamine reduction
A colloidal solution of gold nanoparticles is synthesized with the use of sodium tetrachloroaurate(III) as a precursor, oleylamine as a reducer and surfactant, and 1-octadecene as a solvent. Reaction stages are analyzed in situ by optical (UV-vis) absorption spectroscopy with a simultaneous analysis...
Saved in:
| Published in: | Journal of structural chemistry 2017-12, Vol.58 (7), p.1403-1410 |
|---|---|
| Main Authors: | , , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c316t-4652201e0e6bb2b22a641e39448e4d4a14cb1ca825ecfb01002b3ef9471dd3843 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c316t-4652201e0e6bb2b22a641e39448e4d4a14cb1ca825ecfb01002b3ef9471dd3843 |
| container_end_page | 1410 |
| container_issue | 7 |
| container_start_page | 1403 |
| container_title | Journal of structural chemistry |
| container_volume | 58 |
| creator | Kirichkov, M. V. Guda, A. A. Budnyk, A. P. Lastovina, T. A. Bugaev, A. L. Shapovalov, V. V. Rusalev, Yu. V. Chernyshev, A. V. Soldatov, A. V. |
| description | A colloidal solution of gold nanoparticles is synthesized with the use of sodium tetrachloroaurate(III) as a precursor, oleylamine as a reducer and surfactant, and 1-octadecene as a solvent. Reaction stages are analyzed
in situ
by optical (UV-vis) absorption spectroscopy with a simultaneous analysis of particle sizes by dynamic light scattering and X-ray absorption near edge spectroscopy for the analysis of the gold oxidation state. After the synthesis the size of obtained nanoparticles is determined by transmission electron microscopy. The analysis of the obtained experimental data reveals the presence of three main steps in the reduction reaction mechanism, corresponding to Au
3+
, Au
+
, Au
0
, which enables the construction of the reaction model. The reaction mechanism involves the formation of gold(I) complexes with oleylamine, followed by polymerization and the formation of gold nanoclusters coated with oleylamine. |
| doi_str_mv | 10.1134/S0022476617070186 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1982332713</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1982332713</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-4652201e0e6bb2b22a641e39448e4d4a14cb1ca825ecfb01002b3ef9471dd3843</originalsourceid><addsrcrecordid>eNp1kE9LxDAUxIMouK5-AG8Bz9W8JJu0R1n8BwsedM8lSV_XLt2mJumh397W9SCIpwdv5jcwQ8g1sFsAIe_eGONcaqVAM80gVydkASstslzr4pQsZjmb9XNyEeOeMVbkhVqQ7UtHY5MGajrTjrGJ1Nc0fSCtfTiY1PhJTth_v3e-rWhnOt-bkBrXYqR2pL7FsTWHpkMasBrczFySs9q0Ea9-7pJsHx_e18_Z5vXpZX2_yZwAlTKpVpwzQIbKWm45N0oCikLKHGUlDUhnwZmcr9DVlsFUwgqsC6mhqkQuxZLcHHP74D8HjKnc-yFMTWIJRc6F4BrE5IKjywUfY8C67ENzMGEsgZXzeuWf9SaGH5k4ebsdhl_J_0JfgDtxCQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1982332713</pqid></control><display><type>article</type><title>In situ analysis of the formation steps of gold nanoparticles by oleylamine reduction</title><source>Springer Nature</source><creator>Kirichkov, M. V. ; Guda, A. A. ; Budnyk, A. P. ; Lastovina, T. A. ; Bugaev, A. L. ; Shapovalov, V. V. ; Rusalev, Yu. V. ; Chernyshev, A. V. ; Soldatov, A. V.</creator><creatorcontrib>Kirichkov, M. V. ; Guda, A. A. ; Budnyk, A. P. ; Lastovina, T. A. ; Bugaev, A. L. ; Shapovalov, V. V. ; Rusalev, Yu. V. ; Chernyshev, A. V. ; Soldatov, A. V.</creatorcontrib><description>A colloidal solution of gold nanoparticles is synthesized with the use of sodium tetrachloroaurate(III) as a precursor, oleylamine as a reducer and surfactant, and 1-octadecene as a solvent. Reaction stages are analyzed
in situ
by optical (UV-vis) absorption spectroscopy with a simultaneous analysis of particle sizes by dynamic light scattering and X-ray absorption near edge spectroscopy for the analysis of the gold oxidation state. After the synthesis the size of obtained nanoparticles is determined by transmission electron microscopy. The analysis of the obtained experimental data reveals the presence of three main steps in the reduction reaction mechanism, corresponding to Au
3+
, Au
+
, Au
0
, which enables the construction of the reaction model. The reaction mechanism involves the formation of gold(I) complexes with oleylamine, followed by polymerization and the formation of gold nanoclusters coated with oleylamine.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476617070186</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Electron microscopy ; Gold ; Inorganic Chemistry ; Molecular ; Nanoparticles ; Optical and Plasma Physics ; Oxidation ; Photon correlation spectroscopy ; Physical Chemistry ; Reaction mechanisms ; Reduction ; Solid State Physics ; Spectroscopic analysis ; Spectrum analysis ; Valence</subject><ispartof>Journal of structural chemistry, 2017-12, Vol.58 (7), p.1403-1410</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-4652201e0e6bb2b22a641e39448e4d4a14cb1ca825ecfb01002b3ef9471dd3843</citedby><cites>FETCH-LOGICAL-c316t-4652201e0e6bb2b22a641e39448e4d4a14cb1ca825ecfb01002b3ef9471dd3843</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Kirichkov, M. V.</creatorcontrib><creatorcontrib>Guda, A. A.</creatorcontrib><creatorcontrib>Budnyk, A. P.</creatorcontrib><creatorcontrib>Lastovina, T. A.</creatorcontrib><creatorcontrib>Bugaev, A. L.</creatorcontrib><creatorcontrib>Shapovalov, V. V.</creatorcontrib><creatorcontrib>Rusalev, Yu. V.</creatorcontrib><creatorcontrib>Chernyshev, A. V.</creatorcontrib><creatorcontrib>Soldatov, A. V.</creatorcontrib><title>In situ analysis of the formation steps of gold nanoparticles by oleylamine reduction</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>A colloidal solution of gold nanoparticles is synthesized with the use of sodium tetrachloroaurate(III) as a precursor, oleylamine as a reducer and surfactant, and 1-octadecene as a solvent. Reaction stages are analyzed
in situ
by optical (UV-vis) absorption spectroscopy with a simultaneous analysis of particle sizes by dynamic light scattering and X-ray absorption near edge spectroscopy for the analysis of the gold oxidation state. After the synthesis the size of obtained nanoparticles is determined by transmission electron microscopy. The analysis of the obtained experimental data reveals the presence of three main steps in the reduction reaction mechanism, corresponding to Au
3+
, Au
+
, Au
0
, which enables the construction of the reaction model. The reaction mechanism involves the formation of gold(I) complexes with oleylamine, followed by polymerization and the formation of gold nanoclusters coated with oleylamine.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electron microscopy</subject><subject>Gold</subject><subject>Inorganic Chemistry</subject><subject>Molecular</subject><subject>Nanoparticles</subject><subject>Optical and Plasma Physics</subject><subject>Oxidation</subject><subject>Photon correlation spectroscopy</subject><subject>Physical Chemistry</subject><subject>Reaction mechanisms</subject><subject>Reduction</subject><subject>Solid State Physics</subject><subject>Spectroscopic analysis</subject><subject>Spectrum analysis</subject><subject>Valence</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LxDAUxIMouK5-AG8Bz9W8JJu0R1n8BwsedM8lSV_XLt2mJumh397W9SCIpwdv5jcwQ8g1sFsAIe_eGONcaqVAM80gVydkASstslzr4pQsZjmb9XNyEeOeMVbkhVqQ7UtHY5MGajrTjrGJ1Nc0fSCtfTiY1PhJTth_v3e-rWhnOt-bkBrXYqR2pL7FsTWHpkMasBrczFySs9q0Ea9-7pJsHx_e18_Z5vXpZX2_yZwAlTKpVpwzQIbKWm45N0oCikLKHGUlDUhnwZmcr9DVlsFUwgqsC6mhqkQuxZLcHHP74D8HjKnc-yFMTWIJRc6F4BrE5IKjywUfY8C67ENzMGEsgZXzeuWf9SaGH5k4ebsdhl_J_0JfgDtxCQ</recordid><startdate>20171201</startdate><enddate>20171201</enddate><creator>Kirichkov, M. V.</creator><creator>Guda, A. A.</creator><creator>Budnyk, A. P.</creator><creator>Lastovina, T. A.</creator><creator>Bugaev, A. L.</creator><creator>Shapovalov, V. V.</creator><creator>Rusalev, Yu. V.</creator><creator>Chernyshev, A. V.</creator><creator>Soldatov, A. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20171201</creationdate><title>In situ analysis of the formation steps of gold nanoparticles by oleylamine reduction</title><author>Kirichkov, M. V. ; Guda, A. A. ; Budnyk, A. P. ; Lastovina, T. A. ; Bugaev, A. L. ; Shapovalov, V. V. ; Rusalev, Yu. V. ; Chernyshev, A. V. ; Soldatov, A. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-4652201e0e6bb2b22a641e39448e4d4a14cb1ca825ecfb01002b3ef9471dd3843</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electron microscopy</topic><topic>Gold</topic><topic>Inorganic Chemistry</topic><topic>Molecular</topic><topic>Nanoparticles</topic><topic>Optical and Plasma Physics</topic><topic>Oxidation</topic><topic>Photon correlation spectroscopy</topic><topic>Physical Chemistry</topic><topic>Reaction mechanisms</topic><topic>Reduction</topic><topic>Solid State Physics</topic><topic>Spectroscopic analysis</topic><topic>Spectrum analysis</topic><topic>Valence</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kirichkov, M. V.</creatorcontrib><creatorcontrib>Guda, A. A.</creatorcontrib><creatorcontrib>Budnyk, A. P.</creatorcontrib><creatorcontrib>Lastovina, T. A.</creatorcontrib><creatorcontrib>Bugaev, A. L.</creatorcontrib><creatorcontrib>Shapovalov, V. V.</creatorcontrib><creatorcontrib>Rusalev, Yu. V.</creatorcontrib><creatorcontrib>Chernyshev, A. V.</creatorcontrib><creatorcontrib>Soldatov, A. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kirichkov, M. V.</au><au>Guda, A. A.</au><au>Budnyk, A. P.</au><au>Lastovina, T. A.</au><au>Bugaev, A. L.</au><au>Shapovalov, V. V.</au><au>Rusalev, Yu. V.</au><au>Chernyshev, A. V.</au><au>Soldatov, A. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>In situ analysis of the formation steps of gold nanoparticles by oleylamine reduction</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2017-12-01</date><risdate>2017</risdate><volume>58</volume><issue>7</issue><spage>1403</spage><epage>1410</epage><pages>1403-1410</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>A colloidal solution of gold nanoparticles is synthesized with the use of sodium tetrachloroaurate(III) as a precursor, oleylamine as a reducer and surfactant, and 1-octadecene as a solvent. Reaction stages are analyzed
in situ
by optical (UV-vis) absorption spectroscopy with a simultaneous analysis of particle sizes by dynamic light scattering and X-ray absorption near edge spectroscopy for the analysis of the gold oxidation state. After the synthesis the size of obtained nanoparticles is determined by transmission electron microscopy. The analysis of the obtained experimental data reveals the presence of three main steps in the reduction reaction mechanism, corresponding to Au
3+
, Au
+
, Au
0
, which enables the construction of the reaction model. The reaction mechanism involves the formation of gold(I) complexes with oleylamine, followed by polymerization and the formation of gold nanoclusters coated with oleylamine.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476617070186</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-4766 |
| ispartof | Journal of structural chemistry, 2017-12, Vol.58 (7), p.1403-1410 |
| issn | 0022-4766 1573-8779 |
| language | eng |
| recordid | cdi_proquest_journals_1982332713 |
| source | Springer Nature |
| subjects | Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Electron microscopy Gold Inorganic Chemistry Molecular Nanoparticles Optical and Plasma Physics Oxidation Photon correlation spectroscopy Physical Chemistry Reaction mechanisms Reduction Solid State Physics Spectroscopic analysis Spectrum analysis Valence |
| title | In situ analysis of the formation steps of gold nanoparticles by oleylamine reduction |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-12T23%3A17%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=In%20situ%20analysis%20of%20the%20formation%20steps%20of%20gold%20nanoparticles%20by%20oleylamine%20reduction&rft.jtitle=Journal%20of%20structural%20chemistry&rft.au=Kirichkov,%20M.%20V.&rft.date=2017-12-01&rft.volume=58&rft.issue=7&rft.spage=1403&rft.epage=1410&rft.pages=1403-1410&rft.issn=0022-4766&rft.eissn=1573-8779&rft_id=info:doi/10.1134/S0022476617070186&rft_dat=%3Cproquest_cross%3E1982332713%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c316t-4652201e0e6bb2b22a641e39448e4d4a14cb1ca825ecfb01002b3ef9471dd3843%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1982332713&rft_id=info:pmid/&rfr_iscdi=true |