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Influence of argon and oxygen pressure ratio on bipolar-resistive switching characteristics of CeO2−x thin films deposited at room temperature
Cerium oxide (CeO 2−x ) film was deposited on Pt/Ti/SiO 2 /Si substrate by rf magnetron sputtering at room temperature. Resistive switching characteristics of these ceria films have been improved by increasing oxygen content during deposition process. Endurance and statistical analyses indicate that...
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Published in: | Applied physics. A, Materials science & processing Materials science & processing, 2018-02, Vol.124 (2), p.1-10, Article 89 |
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Main Authors: | , , , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Cerium oxide (CeO
2−x
) film was deposited on Pt/Ti/SiO
2
/Si substrate by rf magnetron sputtering at room temperature. Resistive switching characteristics of these ceria films have been improved by increasing oxygen content during deposition process. Endurance and statistical analyses indicate that the operating stability of CeO
2−x
-based memory is highly dependent on the oxygen content. Results indicate that CeO
2−x
film-based RRAM devices exhibit optimum performance when fabricated at an argon/oxygen ratio of 6:24. An increase in the oxygen content introduced during CeO
2−x
film deposition not only stabilizes the conventional bipolar RS but also improves excellent switching uniformity such as large ON/OFF ratio (10
2
), excellent switching device-to-device uniformity and good sweep endurance over ~ 500 repeated RS cycles. Conduction in the low-resistance state (LRS) as well as in the low bias field region in the high-resistance state (HRS) is found to be Ohmic and thus supports the conductive filament (CF) theory. In the high voltage region of HRS, space charge limited conduction (SCLC) and Schottky emission are found to be the dominant conduction mechanisms. A feasible filamentary RS mechanism based on the movement of oxygen ions/vacancies under the bias voltage has been discussed. |
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ISSN: | 0947-8396 1432-0630 |
DOI: | 10.1007/s00339-017-1512-2 |