Selective quasi-hydrolysis of cyano group in 6-hydroxypiperidine-3,4,4-tricarbonitriles

Reactions of 3,3-dialkyl-4-oxoalkane-1,1,2,2-tetracarbonitriles with water in the presence of pyruvic acid are accompanied by selective quasi-hydrolysis of cyano groups in intermediate 6-hydroxypiperidine-3,4,4-tricarbonitriles.

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Bibliographic Details
Published in:Russian journal of organic chemistry 2017-12, Vol.53 (12), p.1828-1832
Main Authors: Lipin, K. V., Fedoseev, S. V., Ershov, O. V., Tafeenko, V. A.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Cyano groups
Hydrolysis
Organic Chemistry
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Description
Summary:Reactions of 3,3-dialkyl-4-oxoalkane-1,1,2,2-tetracarbonitriles with water in the presence of pyruvic acid are accompanied by selective quasi-hydrolysis of cyano groups in intermediate 6-hydroxypiperidine-3,4,4-tricarbonitriles.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428017120077