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The Effectiveness of Zn Leaching from EAFD Using Caustic Soda
Electric arc furnace dust (EAFD) is a toxic waste which is mainly rich in iron oxide, zinc, and lead. Hydrometallurgical extraction of zinc from Jordanian EAFD in alkaline medium was investigated; NaOH, NaHCO 3 , and Na 2 CO 3 were used as leaching agents. The pH values for the prepared solutions we...
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| Published in: | Water, air, and soil pollution air, and soil pollution, 2018-02, Vol.229 (2), p.1-10, Article 33 |
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| cites | cdi_FETCH-LOGICAL-c383t-b11004bb909705528caab73bfcd815a6c4cc3d2587b57185aacd728e3c8653853 |
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| container_title | Water, air, and soil pollution |
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| creator | Al-Makhadmeh, Leema A. Batiha, Mohammad A. Al-Harahsheh, Mohammad S. Altarawneh, Ibrahem S. Rawadieh, Saleh E. |
| description | Electric arc furnace dust (EAFD) is a toxic waste which is mainly rich in iron oxide, zinc, and lead. Hydrometallurgical extraction of zinc from Jordanian EAFD in alkaline medium was investigated; NaOH, NaHCO
3
, and Na
2
CO
3
were used as leaching agents. The pH values for the prepared solutions were 8.3, 8.2, and 12.55 for NaHCO
3
, Na
2
CO
3
, and NaOH, respectively. The effect of NaOH concentration (1, 3, 5, 7, and 9 M), contact time (5 min to 3 h), temperature (20, 40, and 60), and solid-to-liquid ratio (SLR; 20, 40, 80, and 120 mg/ml) on the leachability of zinc from EAFD were tested. The initial EAFD and the resulting leach residues were characterized using X-ray diffraction (XRD) and X-ray fluorescence (XRF). EAFD contained 25.9% Zn, 18.0% Fe, and 3.2% Pb. A maximum zinc recovery of 92.9% was achieved using 6 M NaOH at 60 °C with solid loading of 20 g/L and 3 h leaching time. NaHCO
3
and Na
2
CO
3
were not efficient leaching agents for Zn extraction since the recoveries were only 2.6 and 4.5%, respectively. Zn and Pb were depleted in the residues with an
E
-factor of 0.5–0.6 and 0.1–0.25, respectively. Iron was enriched in the residues; the
E
-factor was around 2. The EAFD contained mainly zincite, franklinite, and magnetite. After 3 h leaching, only traces of zincite exist in the residues, while sylvite and halite were completely dissolved. |
| doi_str_mv | 10.1007/s11270-018-3694-4 |
| format | article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_1993210390</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A523919696</galeid><sourcerecordid>A523919696</sourcerecordid><originalsourceid>FETCH-LOGICAL-c383t-b11004bb909705528caab73bfcd815a6c4cc3d2587b57185aacd728e3c8653853</originalsourceid><addsrcrecordid>eNp1kMtKAzEUhoMoWKsP4C7gOjWXySRZuCi1VaHgwnbjJmQySZvSztRkKvj2poygguYswjn837n8AFwTPCIYi9tECBUYYSIRK1WBihMwIFwwRBWjp2CAcaFQqYQ6BxcpbXB-SooBuFusHZx672wX3l3jUoKth68NnDtj16FZQR_bHZyOZ_dwmY75xBxSFyx8aWtzCc682SZ39fUPwXI2XUwe0fz54WkyniPLJOtQRfKORVUprATmnEprTCVY5W0tCTelLaxlNeVSVFwQyY2xtaDSMStLziRnQ3DT993H9u3gUqc37SE2eaQmKh9IMFP4W7UyW6dD49suGrsLyeoxp0wRVaoyq0Z_qHLUbhds2zgfcv0XQHrAxjal6Lzex7Az8UMTrI_m6958nc3XR_N1kRnaMylrm5WLPxb-F_oE6H6C0Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1993210390</pqid></control><display><type>article</type><title>The Effectiveness of Zn Leaching from EAFD Using Caustic Soda</title><source>ABI/INFORM Global</source><source>Springer Nature:Jisc Collections:Springer Nature Read and Publish 2023-2025: Springer Reading List</source><creator>Al-Makhadmeh, Leema A. ; Batiha, Mohammad A. ; Al-Harahsheh, Mohammad S. ; Altarawneh, Ibrahem S. ; Rawadieh, Saleh E.</creator><creatorcontrib>Al-Makhadmeh, Leema A. ; Batiha, Mohammad A. ; Al-Harahsheh, Mohammad S. ; Altarawneh, Ibrahem S. ; Rawadieh, Saleh E.</creatorcontrib><description>Electric arc furnace dust (EAFD) is a toxic waste which is mainly rich in iron oxide, zinc, and lead. Hydrometallurgical extraction of zinc from Jordanian EAFD in alkaline medium was investigated; NaOH, NaHCO
3
, and Na
2
CO
3
were used as leaching agents. The pH values for the prepared solutions were 8.3, 8.2, and 12.55 for NaHCO
3
, Na
2
CO
3
, and NaOH, respectively. The effect of NaOH concentration (1, 3, 5, 7, and 9 M), contact time (5 min to 3 h), temperature (20, 40, and 60), and solid-to-liquid ratio (SLR; 20, 40, 80, and 120 mg/ml) on the leachability of zinc from EAFD were tested. The initial EAFD and the resulting leach residues were characterized using X-ray diffraction (XRD) and X-ray fluorescence (XRF). EAFD contained 25.9% Zn, 18.0% Fe, and 3.2% Pb. A maximum zinc recovery of 92.9% was achieved using 6 M NaOH at 60 °C with solid loading of 20 g/L and 3 h leaching time. NaHCO
3
and Na
2
CO
3
were not efficient leaching agents for Zn extraction since the recoveries were only 2.6 and 4.5%, respectively. Zn and Pb were depleted in the residues with an
E
-factor of 0.5–0.6 and 0.1–0.25, respectively. Iron was enriched in the residues; the
E
-factor was around 2. The EAFD contained mainly zincite, franklinite, and magnetite. After 3 h leaching, only traces of zincite exist in the residues, while sylvite and halite were completely dissolved.</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1007/s11270-018-3694-4</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Atmospheric particulates ; Atmospheric Protection/Air Quality Control/Air Pollution ; Caustic leaching ; Caustic soda ; Chemical engineering ; Climate Change/Climate Change Impacts ; Dust ; Dust storms ; Earth and Environmental Science ; Electric contacts ; Environment ; Environmental monitoring ; Ferric oxide ; Fluorescence ; Furnaces ; Halite ; Halites ; Hazardous wastes ; Hydrogeology ; Hydrometallurgy ; Iron ; Iron compounds ; Iron oxides ; Leaching ; Lead ; Magnetite ; Metals ; pH effects ; Recycling ; Residues ; Sodium hydroxide ; Soil Science & Conservation ; Solutions ; Sylvite ; Toxic wastes ; Water Quality/Water Pollution ; X-ray diffraction ; X-ray fluorescence ; X-ray spectroscopy ; X-rays ; Zinc ; Zinc oxide ; Zinc oxides</subject><ispartof>Water, air, and soil pollution, 2018-02, Vol.229 (2), p.1-10, Article 33</ispartof><rights>Springer International Publishing AG, part of Springer Nature 2018</rights><rights>COPYRIGHT 2018 Springer</rights><rights>Water, Air, & Soil Pollution is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c383t-b11004bb909705528caab73bfcd815a6c4cc3d2587b57185aacd728e3c8653853</citedby><cites>FETCH-LOGICAL-c383t-b11004bb909705528caab73bfcd815a6c4cc3d2587b57185aacd728e3c8653853</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/1993210390/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/1993210390?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,777,781,11669,27905,27906,36041,44344,74644</link.rule.ids></links><search><creatorcontrib>Al-Makhadmeh, Leema A.</creatorcontrib><creatorcontrib>Batiha, Mohammad A.</creatorcontrib><creatorcontrib>Al-Harahsheh, Mohammad S.</creatorcontrib><creatorcontrib>Altarawneh, Ibrahem S.</creatorcontrib><creatorcontrib>Rawadieh, Saleh E.</creatorcontrib><title>The Effectiveness of Zn Leaching from EAFD Using Caustic Soda</title><title>Water, air, and soil pollution</title><addtitle>Water Air Soil Pollut</addtitle><description>Electric arc furnace dust (EAFD) is a toxic waste which is mainly rich in iron oxide, zinc, and lead. Hydrometallurgical extraction of zinc from Jordanian EAFD in alkaline medium was investigated; NaOH, NaHCO
3
, and Na
2
CO
3
were used as leaching agents. The pH values for the prepared solutions were 8.3, 8.2, and 12.55 for NaHCO
3
, Na
2
CO
3
, and NaOH, respectively. The effect of NaOH concentration (1, 3, 5, 7, and 9 M), contact time (5 min to 3 h), temperature (20, 40, and 60), and solid-to-liquid ratio (SLR; 20, 40, 80, and 120 mg/ml) on the leachability of zinc from EAFD were tested. The initial EAFD and the resulting leach residues were characterized using X-ray diffraction (XRD) and X-ray fluorescence (XRF). EAFD contained 25.9% Zn, 18.0% Fe, and 3.2% Pb. A maximum zinc recovery of 92.9% was achieved using 6 M NaOH at 60 °C with solid loading of 20 g/L and 3 h leaching time. NaHCO
3
and Na
2
CO
3
were not efficient leaching agents for Zn extraction since the recoveries were only 2.6 and 4.5%, respectively. Zn and Pb were depleted in the residues with an
E
-factor of 0.5–0.6 and 0.1–0.25, respectively. Iron was enriched in the residues; the
E
-factor was around 2. The EAFD contained mainly zincite, franklinite, and magnetite. After 3 h leaching, only traces of zincite exist in the residues, while sylvite and halite were completely dissolved.</description><subject>Atmospheric particulates</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Caustic leaching</subject><subject>Caustic soda</subject><subject>Chemical engineering</subject><subject>Climate Change/Climate Change Impacts</subject><subject>Dust</subject><subject>Dust storms</subject><subject>Earth and Environmental Science</subject><subject>Electric contacts</subject><subject>Environment</subject><subject>Environmental monitoring</subject><subject>Ferric oxide</subject><subject>Fluorescence</subject><subject>Furnaces</subject><subject>Halite</subject><subject>Halites</subject><subject>Hazardous wastes</subject><subject>Hydrogeology</subject><subject>Hydrometallurgy</subject><subject>Iron</subject><subject>Iron compounds</subject><subject>Iron oxides</subject><subject>Leaching</subject><subject>Lead</subject><subject>Magnetite</subject><subject>Metals</subject><subject>pH effects</subject><subject>Recycling</subject><subject>Residues</subject><subject>Sodium hydroxide</subject><subject>Soil Science & Conservation</subject><subject>Solutions</subject><subject>Sylvite</subject><subject>Toxic wastes</subject><subject>Water Quality/Water Pollution</subject><subject>X-ray diffraction</subject><subject>X-ray fluorescence</subject><subject>X-ray spectroscopy</subject><subject>X-rays</subject><subject>Zinc</subject><subject>Zinc oxide</subject><subject>Zinc oxides</subject><issn>0049-6979</issn><issn>1573-2932</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>M0C</sourceid><recordid>eNp1kMtKAzEUhoMoWKsP4C7gOjWXySRZuCi1VaHgwnbjJmQySZvSztRkKvj2poygguYswjn837n8AFwTPCIYi9tECBUYYSIRK1WBihMwIFwwRBWjp2CAcaFQqYQ6BxcpbXB-SooBuFusHZx672wX3l3jUoKth68NnDtj16FZQR_bHZyOZ_dwmY75xBxSFyx8aWtzCc682SZ39fUPwXI2XUwe0fz54WkyniPLJOtQRfKORVUprATmnEprTCVY5W0tCTelLaxlNeVSVFwQyY2xtaDSMStLziRnQ3DT993H9u3gUqc37SE2eaQmKh9IMFP4W7UyW6dD49suGrsLyeoxp0wRVaoyq0Z_qHLUbhds2zgfcv0XQHrAxjal6Lzex7Az8UMTrI_m6958nc3XR_N1kRnaMylrm5WLPxb-F_oE6H6C0Q</recordid><startdate>20180201</startdate><enddate>20180201</enddate><creator>Al-Makhadmeh, Leema A.</creator><creator>Batiha, Mohammad A.</creator><creator>Al-Harahsheh, Mohammad S.</creator><creator>Altarawneh, Ibrahem S.</creator><creator>Rawadieh, Saleh E.</creator><general>Springer International 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Effectiveness of Zn Leaching from EAFD Using Caustic Soda</title><author>Al-Makhadmeh, Leema A. ; Batiha, Mohammad A. ; Al-Harahsheh, Mohammad S. ; Altarawneh, Ibrahem S. ; Rawadieh, Saleh E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c383t-b11004bb909705528caab73bfcd815a6c4cc3d2587b57185aacd728e3c8653853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Atmospheric particulates</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Caustic leaching</topic><topic>Caustic soda</topic><topic>Chemical engineering</topic><topic>Climate Change/Climate Change Impacts</topic><topic>Dust</topic><topic>Dust storms</topic><topic>Earth and Environmental Science</topic><topic>Electric contacts</topic><topic>Environment</topic><topic>Environmental monitoring</topic><topic>Ferric oxide</topic><topic>Fluorescence</topic><topic>Furnaces</topic><topic>Halite</topic><topic>Halites</topic><topic>Hazardous wastes</topic><topic>Hydrogeology</topic><topic>Hydrometallurgy</topic><topic>Iron</topic><topic>Iron compounds</topic><topic>Iron oxides</topic><topic>Leaching</topic><topic>Lead</topic><topic>Magnetite</topic><topic>Metals</topic><topic>pH effects</topic><topic>Recycling</topic><topic>Residues</topic><topic>Sodium hydroxide</topic><topic>Soil Science & Conservation</topic><topic>Solutions</topic><topic>Sylvite</topic><topic>Toxic wastes</topic><topic>Water Quality/Water Pollution</topic><topic>X-ray diffraction</topic><topic>X-ray fluorescence</topic><topic>X-ray spectroscopy</topic><topic>X-rays</topic><topic>Zinc</topic><topic>Zinc oxide</topic><topic>Zinc oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Al-Makhadmeh, Leema A.</creatorcontrib><creatorcontrib>Batiha, Mohammad 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Basic</collection><jtitle>Water, air, and soil pollution</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Al-Makhadmeh, Leema A.</au><au>Batiha, Mohammad A.</au><au>Al-Harahsheh, Mohammad S.</au><au>Altarawneh, Ibrahem S.</au><au>Rawadieh, Saleh E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Effectiveness of Zn Leaching from EAFD Using Caustic Soda</atitle><jtitle>Water, air, and soil pollution</jtitle><stitle>Water Air Soil Pollut</stitle><date>2018-02-01</date><risdate>2018</risdate><volume>229</volume><issue>2</issue><spage>1</spage><epage>10</epage><pages>1-10</pages><artnum>33</artnum><issn>0049-6979</issn><eissn>1573-2932</eissn><abstract>Electric arc furnace dust (EAFD) is a toxic waste which is mainly rich in iron oxide, zinc, and lead. Hydrometallurgical extraction of zinc from Jordanian EAFD in alkaline medium was investigated; NaOH, NaHCO
3
, and Na
2
CO
3
were used as leaching agents. The pH values for the prepared solutions were 8.3, 8.2, and 12.55 for NaHCO
3
, Na
2
CO
3
, and NaOH, respectively. The effect of NaOH concentration (1, 3, 5, 7, and 9 M), contact time (5 min to 3 h), temperature (20, 40, and 60), and solid-to-liquid ratio (SLR; 20, 40, 80, and 120 mg/ml) on the leachability of zinc from EAFD were tested. The initial EAFD and the resulting leach residues were characterized using X-ray diffraction (XRD) and X-ray fluorescence (XRF). EAFD contained 25.9% Zn, 18.0% Fe, and 3.2% Pb. A maximum zinc recovery of 92.9% was achieved using 6 M NaOH at 60 °C with solid loading of 20 g/L and 3 h leaching time. NaHCO
3
and Na
2
CO
3
were not efficient leaching agents for Zn extraction since the recoveries were only 2.6 and 4.5%, respectively. Zn and Pb were depleted in the residues with an
E
-factor of 0.5–0.6 and 0.1–0.25, respectively. Iron was enriched in the residues; the
E
-factor was around 2. The EAFD contained mainly zincite, franklinite, and magnetite. After 3 h leaching, only traces of zincite exist in the residues, while sylvite and halite were completely dissolved.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11270-018-3694-4</doi><tpages>10</tpages></addata></record> |
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| ispartof | Water, air, and soil pollution, 2018-02, Vol.229 (2), p.1-10, Article 33 |
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| language | eng |
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| source | ABI/INFORM Global; Springer Nature:Jisc Collections:Springer Nature Read and Publish 2023-2025: Springer Reading List |
| subjects | Atmospheric particulates Atmospheric Protection/Air Quality Control/Air Pollution Caustic leaching Caustic soda Chemical engineering Climate Change/Climate Change Impacts Dust Dust storms Earth and Environmental Science Electric contacts Environment Environmental monitoring Ferric oxide Fluorescence Furnaces Halite Halites Hazardous wastes Hydrogeology Hydrometallurgy Iron Iron compounds Iron oxides Leaching Lead Magnetite Metals pH effects Recycling Residues Sodium hydroxide Soil Science & Conservation Solutions Sylvite Toxic wastes Water Quality/Water Pollution X-ray diffraction X-ray fluorescence X-ray spectroscopy X-rays Zinc Zinc oxide Zinc oxides |
| title | The Effectiveness of Zn Leaching from EAFD Using Caustic Soda |
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