Liquid–Liquid Equilibrium and Thermodynamic Modeling of Aqueous Two-Phase System Containing Polypropylene Glycol and NaClO4 at T = (288.15 and 298.15) K

• Published in: Journal of solution chemistry 2018, Vol.47 (1), p.1-25
• Main Authors: Hamta, Afshin, Mohammadi, Asma, Dehghani, Mohammad Reza, Feyzi, Farzaneh
• Format: Article
• Language: English
• Subjects: Atmospheric models; Binary systems; Chemistry; Chemistry and Materials Science; Condensed Matter Physics; Equilibrium; Geochemistry; Industrial Chemistry/Chemical Engineering; Inorganic Chemistry; Mathematical models; Oceanography; Phase equilibria; Physical Chemistry; Polypropylene glycol; Temperature; Temperature dependence; Temperature effects
• ISSN: 0095-9782; 1572-8927
• DOI: 10.1007/s10953-017-0704-x

In this work the phase equilibrium of an aqueous two phase system (ATPS) containing polypropylene glycol (PPG, molecular weight = 425 kg·mol −1 ) and NaClO 4 was investigated at atmospheric pressure and at 288.15 and 298.15 K. Two phase regions and composition of phases were determined. Our results show that as the temperature increases, the two-phase region expands. Also, the extended UNIQUAC (E-UNIQUAC) equation was used to correlate the equilibrium data. To reduce the number of adjustable parameters, ATPSs composed of PEG and PPG were collected from the literature and simultaneously correlated using the E-UNIQUAC model. Also, the effect of temperature on the liquid–liquid equilibrium (LLE) was considered by using temperature-dependent parameters. In the modeling, two different scenarios were supposed. In the first, polymer and salt were treated as solutes (Case A), while in the second, the pseudo-solvent approach was considered (Case B). The results showed good agreement with experimental data in both cases. The average absolute deviation of the model using Case B was about 0.2% and that for Case A was about 2% in the ATPS composed of PEG. Meanwhile, the reported errors in the ATPS containing PPG for Case A and Case B were almost equal.