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Growth and optical properties of In x Ga1−x P nanowires synthesized by selective-area epitaxy

Ternary III–V nanowires (NWs) cover a wide range of wavelengths in the solar spectrum and would greatly benefit from being synthesized as position-controlled arrays for improved vertical yield, reproducibility, and tunable optical absorption. Here, we report on successful selective-area epitaxy of m...

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Bibliographic Details
Published in:Nano research 2017-02, Vol.10 (2), p.672-682
Main Authors: Berg, Alexander, Caroff, Philippe, Shahid, Naeem, Lockrey, Mark N., Yuan, Xiaoming, Borgström, Magnus T., Tan, Hark Hoe, Jagadish, Chennupati
Format: Article
Language:English
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Summary:Ternary III–V nanowires (NWs) cover a wide range of wavelengths in the solar spectrum and would greatly benefit from being synthesized as position-controlled arrays for improved vertical yield, reproducibility, and tunable optical absorption. Here, we report on successful selective-area epitaxy of metal-particle-free vertical InxGa1−xP NW arrays using metal–organic vapor phase epitaxy and detail their optical properties. A systematic growth study establishes the range of suitable growth parameters to obtain uniform NW growth over a large array. The optical properties of the NWs were characterized by room-temperature cathodoluminescence spectroscopy. Tunability of the emission wavelength from 870 nm to approximately 800 nm was achieved. Transmission electron microscopy and energy dispersive X-ray measurements performed on cross-section samples revealed a pure wurtzite crystal structure with very few stacking faults and a slight composition gradient along the NW growth axis.
ISSN:1998-0124
1998-0000
DOI:10.1007/s12274-016-1325-1