Dynamic volatilization behavior of Pb and Cd during fixed bed waste incineration: Effect of chlorine and calcium oxide

• Published in: Fuel (Guildford) 2017-03, Vol.192, p.1-9
• Main Authors: Wang, Xinye, Huang, Yaji, Liu, Changqi, Zhang, Shuaiyi, Wang, Yongxing, Piao, Guilin
• Format: Article
• Language: English
• Subjects: Aluminum oxide; Atmosphere; Cadmium; Calcium; Calcium oxide; Chlorination; Chlorine; Combustion; Fixed bed; Fixed bed reactors; High temperature; Incineration; Lead; Lime; Melting points; Polyvinyl chloride; Silicon dioxide; Sodium chloride; Solid wastes; Volatilization; Waste disposal
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2016.12.002

•The dynamic volatilization data were obtained by continuous interval sampling.•Fixed bed generated reducing atmosphere which affected volatilization greatly.•PVC chlorinated PbO and CdO indirectly while NaCl chlorinated them directly.•CaO adsorbed HCl from PVC at low temperature but released back at high temperature. Simulated solid waste was incinerated in a fixed bed, while continuously collecting volatized Pb and Cd to investigate the dynamic volatilization behavior. The dynamic data revealed the reducing atmosphere generated by the fixed bed as the main reason for the lower initial volatilization temperatures of Pb and Cd compared to PbO and CdO melting points during chlorine-free incineration. CdO was easier to reduce than PbO; consequently, Cd volatilized stronger than Pb in the chlorine-free fixed bed. However, CdO volatilization was expected to be weaker than PbO volatilization in an air atmosphere. In contrast to the reduction in a fixed bed, the addition of PVC led to indirect chlorination of Pb and Cd at 300–400°C and 400–500°C, respectively and their volatilization was significantly enhanced via chlorination. NaCl directly chlorinated Pb and Cd at comparatively high temperatures of 800–900°C and 700–800°C, respectively via involvement of SiO2 and Al2O3. Moreover, CaO absorbed HCl from PVC, resulting in volatilization inhibition of Pb and Cd at a temperature below 700°C. However, chlorine was released at a higher temperature. Furthermore, CaO had no effect on NaCl-induced volatilization enhancement of Pb and Cd.