Effect of doping with nanosized oxides on thermal properties of the NaNO3–NaClO4 system

Structural and thermodynamic properties of the NaNO 3 –NaClO 4 eutectic system and its composites with nanosized oxides of aluminum and magnesium were studied by differential scanning calorimetry (DSC) and differential thermal analysis (DTA). It has been established that nanocrystalline alumina in N...

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Bibliographic Details
Published in:Journal of thermal analysis and calorimetry 2018-03, Vol.131 (3), p.3169-3173
Main Authors: Amirov, A. M., Gafurov, M. M., Suleymanov, S. I.
Format: Article
Language:English
Subjects:
Aluminum oxide
Analytical Chemistry
Chemistry
Chemistry and Materials Science
Enthalpy
Inorganic Chemistry
Magnesium oxide
Measurement Science and Instrumentation
Physical Chemistry
Polymer Sciences
Product design
Thermal analysis
Thermodynamic properties
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Summary:Structural and thermodynamic properties of the NaNO 3 –NaClO 4 eutectic system and its composites with nanosized oxides of aluminum and magnesium were studied by differential scanning calorimetry (DSC) and differential thermal analysis (DTA). It has been established that nanocrystalline alumina in NaNO 3 –NaClO 4 –RxOy composites exerts a greater influence on the enthalpy of fusion of the eutectic both with the same molar fractions and with the same mass fractions of oxides than magnesium oxide. Thermal properties of the eutectic are affected by specific surface and nature of the nanoscale oxide.
ISSN:1388-6150
1588-2926
DOI:10.1007/s10973-017-6818-y