Reactions catalyzed by a binuclear copper complex: selective oxidation of alkenes to carbonyls with O2

Terminal alkenes were selectively cleaved into ketones and aldehydes catalyzed by a binuclear copper catalyst bearing a simple salicylate ligand with O2 as the oxidant. The reaction was carried out under an atmosphere of O2 (balloon) with 0.5 mol% of catalyst and could be performed on a gram scale,...

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Published in:Catalysis science & technology 2017-01, Vol.7 (23), p.5510-5514
Main Authors: Liu, Yuxia, Xue, Dong, Li, Chaoqun, Xiao, Jianliang, Wang, Chao
Format: Article
Language:English
Subjects:
Aldehydes
Alkenes
Carbonyl compounds
Carbonyls
Catalysis
Catalysts
Chemical reactions
Coordination compounds
Copper
Copper compounds
Ketones
Oxidation
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creator Liu, Yuxia
Xue, Dong
Li, Chaoqun
Xiao, Jianliang
Wang, Chao
description Terminal alkenes were selectively cleaved into ketones and aldehydes catalyzed by a binuclear copper catalyst bearing a simple salicylate ligand with O2 as the oxidant. The reaction was carried out under an atmosphere of O2 (balloon) with 0.5 mol% of catalyst and could be performed on a gram scale, providing a convenient and practical method for the cleavage of terminal alkenes into carbonyl compounds.
doi_str_mv 10.1039/c7cy01757j
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source Royal Society of Chemistry
subjects Aldehydes
Alkenes
Carbonyl compounds
Carbonyls
Catalysis
Catalysts
Chemical reactions
Coordination compounds
Copper
Copper compounds
Ketones
Oxidation
title Reactions catalyzed by a binuclear copper complex: selective oxidation of alkenes to carbonyls with O2
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