High-throughput evaluation of in situ-generated cobalt( iii ) catalysts for acyl fluoride synthesis

Using a high-throughput experimental procedure, a series of cobalt( iii ) complexes of the general formula Cp R Co(I)(X)(L) were prepared and screened for their activity towards the catalytic nucleophilic fluorination of benzoyl chloride. A highly active catalyst was identified, and successfully emp...

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Bibliographic Details
Published in:Catalysis science & technology 2017, Vol.7 (21), p.4996-5003
Main Authors: Lee, Graham M., Clément, Roxanne, Tom Baker, R.
Format: Article
Language:English
Subjects:
Catalysis
Catalysts
Chemical synthesis
Cobalt
Fluorides
Fluorination
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Summary:Using a high-throughput experimental procedure, a series of cobalt( iii ) complexes of the general formula Cp R Co(I)(X)(L) were prepared and screened for their activity towards the catalytic nucleophilic fluorination of benzoyl chloride. A highly active catalyst was identified, and successfully employed in a mild and effective protocol for the synthesis of a group of acyl fluoride compounds.
ISSN:2044-4753
2044-4761
DOI:10.1039/C7CY01519D