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Figure of merit ZT of a thermoelectric device defined from materials properties

While the thermoelectric materials figure of merit is a well defined metric to evaluate thermoelectric materials, it can be a poor metric for maximum thermoelectric device efficiency because of the temperature dependence of the Seebeck coefficient S , the electrical resistivity ρ , and the thermal c...

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Published in:Energy & environmental science 2017-01, Vol.10 (11), p.2280-2283
Main Authors: Snyder, G. Jeffrey, Snyder, Alemayouh H.
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Language:English
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description While the thermoelectric materials figure of merit is a well defined metric to evaluate thermoelectric materials, it can be a poor metric for maximum thermoelectric device efficiency because of the temperature dependence of the Seebeck coefficient S , the electrical resistivity ρ , and the thermal conductivity κ where T is the absolute temperature. Historically the field has used a thermoelectric device figure of merit ZT to characterize a device operating between a hot side temperature T h and cold side temperature T c . While there are many approximate methods to calculate ZT from temperature dependent materials properties, an exact method is given here that uses a simple algorithm that can be performed on a spreadsheet calculator. The figure of merit is defined for a thermoelectric generator using the maximum efficiency of the thermoelectric device η calculated from the exact method.
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subjects Approximation
Electrical resistivity
Figure of merit
Heat conductivity
Historical account
Mathematical analysis
Seebeck effect
Temperature
Temperature dependence
Temperature effects
Thermal conductivity
Thermoelectric generators
Thermoelectric materials
title Figure of merit ZT of a thermoelectric device defined from materials properties
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