Iridium( iii )-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

Cyclometallated iridium( iii ) complexes with 2-phenylpyridine [Ir(ppy) 2 (CNR)Cl] (ppy = (2-phenylpyridinato-C 2 , N ), R = Xyl, Mes), [Ir(ppy) 2 (CNR) 2 ](OTf) (R = Xyl, Mes), and fac -[Ir(ppy) 3 ] catalyse the cross-linking of polysiloxanes exclusively at temperatures above 100 °C leading to lumi...

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Bibliographic Details
Published in:Catalysis science & technology 2017, Vol.7 (24), p.5843-5846
Main Authors: Islamova, Regina M., Dobrynin, Mikhail V., Vlasov, Andrey V., Eremina, Anzhelika A., Kinzhalov, Mikhail A., Kolesnikov, Ilya E., Zolotarev, Andrey A., Masloborodova, Eleonora A., Luzyanin, Konstantin V.
Format: Article
Language:English
Subjects:
Crosslinking
Iridium
Iridium compounds
Polysiloxanes
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Summary:Cyclometallated iridium( iii ) complexes with 2-phenylpyridine [Ir(ppy) 2 (CNR)Cl] (ppy = (2-phenylpyridinato-C 2 , N ), R = Xyl, Mes), [Ir(ppy) 2 (CNR) 2 ](OTf) (R = Xyl, Mes), and fac -[Ir(ppy) 3 ] catalyse the cross-linking of polysiloxanes exclusively at temperatures above 100 °C leading to luminescent rubbers.
ISSN:2044-4753
2044-4761
DOI:10.1039/C7CY02013A