Iridium( iii )-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

Cyclometallated iridium( iii ) complexes with 2-phenylpyridine [Ir(ppy) 2 (CNR)Cl] (ppy = (2-phenylpyridinato-C 2 , N ), R = Xyl, Mes), [Ir(ppy) 2 (CNR) 2 ](OTf) (R = Xyl, Mes), and fac -[Ir(ppy) 3 ] catalyse the cross-linking of polysiloxanes exclusively at temperatures above 100 °C leading to lumi...

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Published in:Catalysis science & technology 2017, Vol.7 (24), p.5843-5846
Main Authors: Islamova, Regina M., Dobrynin, Mikhail V., Vlasov, Andrey V., Eremina, Anzhelika A., Kinzhalov, Mikhail A., Kolesnikov, Ilya E., Zolotarev, Andrey A., Masloborodova, Eleonora A., Luzyanin, Konstantin V.
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Language:English
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Crosslinking
Iridium
Iridium compounds
Polysiloxanes
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container_issue 24
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container_title Catalysis science & technology
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creator Islamova, Regina M.
Dobrynin, Mikhail V.
Vlasov, Andrey V.
Eremina, Anzhelika A.
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Kolesnikov, Ilya E.
Zolotarev, Andrey A.
Masloborodova, Eleonora A.
Luzyanin, Konstantin V.
description Cyclometallated iridium( iii ) complexes with 2-phenylpyridine [Ir(ppy) 2 (CNR)Cl] (ppy = (2-phenylpyridinato-C 2 , N ), R = Xyl, Mes), [Ir(ppy) 2 (CNR) 2 ](OTf) (R = Xyl, Mes), and fac -[Ir(ppy) 3 ] catalyse the cross-linking of polysiloxanes exclusively at temperatures above 100 °C leading to luminescent rubbers.
doi_str_mv 10.1039/C7CY02013A
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subjects Crosslinking
Iridium
Iridium compounds
Polysiloxanes
title Iridium( iii )-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers
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