Fabrication of Pd/CuFe2O4 hybrid nanowires: a heterogeneous catalyst for Heck couplings

The development of environmentally benign transformations is indispensable in organic synthesis. Herein, a hybrid heterogeneous catalyst, palladium(0) on copper ferrite nanowires, has been synthesized, characterized, and for the first time, employed in the Jeffrey Heck reaction between iodoarenes an...

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Bibliographic Details
Published in:New journal of chemistry 2018, Vol.42 (3), p.1646-1654
Main Authors: Lakshminarayana, B, Mahendar, L, Ghosal, P, Sreedhar, B, Satyanarayana, G, Subrahmanyam, Ch
Format: Article
Language:English
Subjects:
Alcohols
Catalysis
Catalysts
Catalytic activity
Chemical synthesis
Copper ferrite
Couplings
Nanowires
Palladium
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Summary:The development of environmentally benign transformations is indispensable in organic synthesis. Herein, a hybrid heterogeneous catalyst, palladium(0) on copper ferrite nanowires, has been synthesized, characterized, and for the first time, employed in the Jeffrey Heck reaction between iodoarenes and allylic alcohols, and good to excellent yields have been obtained. In addition, the catalyst was found to be suitable for the usual Heck coupling. The nanocatalyst was recovered and reused up-to multiple runs without any noticeable loss of its catalytic activity.
ISSN:1144-0546
1369-9261
DOI:10.1039/c7nj04361a