Microwave-assisted synthesis of organically functionalized hexa-molybdovanadates

The microwave-assisted reaction of (TBA) 4 [β-Mo 8 O 24 ] and (TBA) 3 [H 3 V 10 O 28 ] with pentaerythritol or tris(hydroxymethyl)aminomethane yields polyanions with the general formula (TBA) 2 [V 3 Mo 3 O 16 (O 3 –R)] (R: C 5 H 8 OH – 1 ; R: C 4 H 6 NH 2 – 3 ). Post-synthetic esterification of 1 yi...

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Bibliographic Details
Published in:New journal of chemistry 2018, Vol.42 (1), p.25-28
Main Authors: Karoui, H., Ritchie, C.
Format: Article
Language:English
Subjects:
Chemical synthesis
Esterification
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Summary:The microwave-assisted reaction of (TBA) 4 [β-Mo 8 O 24 ] and (TBA) 3 [H 3 V 10 O 28 ] with pentaerythritol or tris(hydroxymethyl)aminomethane yields polyanions with the general formula (TBA) 2 [V 3 Mo 3 O 16 (O 3 –R)] (R: C 5 H 8 OH – 1 ; R: C 4 H 6 NH 2 – 3 ). Post-synthetic esterification of 1 yields the acylated derivative 2 , with all compounds being characterized in the solid and solution state.
ISSN:1144-0546
1369-9261
DOI:10.1039/C7NJ02820B