Polysulfides made from re-purposed waste are sustainable materials for removing iron from water

Water contaminated with Fe 3+ is undesirable because it can result in discoloured plumbing fixtures, clogging, and a poor taste and aesthetic profile for drinking water. At high levels, Fe 3+ can also promote the growth of unwanted bacteria, so environmental agencies and water authorities typically...

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Bibliographic Details
Published in:RSC advances 2018-01, Vol.8 (3), p.1232-1236
Main Authors: Lundquist, Nicholas A, Worthington, Max J. H, Adamson, Nick, Gibson, Christopher T, Johnston, Martin R, Ellis, Amanda V, Chalker, Justin M
Format: Article
Language:English
Subjects:
Chemistry
Contaminants
Cooking
Drinking water
Fixtures
Iron
Polysulfides
Sorbents
Sulfur
Sustainable materials
Wastewater
Water utilities
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Summary:Water contaminated with Fe 3+ is undesirable because it can result in discoloured plumbing fixtures, clogging, and a poor taste and aesthetic profile for drinking water. At high levels, Fe 3+ can also promote the growth of unwanted bacteria, so environmental agencies and water authorities typically regulate the amount of Fe 3+ in municipal water and wastewater. Here, polysulfide sorbents-prepared from elemental sulfur and unsaturated cooking oils-are used to remove Fe 3+ contaminants from water. The sorbent is low-cost and sustainable, as it can be prepared entirely from waste. The preparation of this material using microwave heating and its application in iron capture are two important advances in the growing field of sulfur polymers. A polymer prepared by co-polymerisation of sulfur and canola oil removed Fe 3+ from water. Microwave irradiation was convenient in promoting the polymerisation.
ISSN:2046-2069
2046-2069
DOI:10.1039/c7ra11999b