A new semiconducting 1D Cu( i )–Cu( ii ) mixed-valence coordination polymer with Cu( ii ) dimethylpiperidine–dithiocarbamate and a tetranuclear Cu( i )–Br cluster unit

A novel mixed-valence coordination polymer [CuI4Cu II Br 4 (dmpip-dtc) 2 (CH 3 CN)] n (dmpip-dtc = dimethylpiperidine–dithiocarbamate) with an infinite one-dimensional structure was synthesized and structurally characterized using X-ray diffraction. The electronic properties of the coordination poly...

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Bibliographic Details
Published in:New journal of chemistry 2018, Vol.42 (6), p.3995-3998
Main Authors: Himoto, K., Suzuki, S., Okubo, T., Maekawa, M., Kuroda-Sowa, T.
Format: Article
Language:English
Subjects:
Coordination polymers
Electronic properties
Impedance measurement
Polymers
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Summary:A novel mixed-valence coordination polymer [CuI4Cu II Br 4 (dmpip-dtc) 2 (CH 3 CN)] n (dmpip-dtc = dimethylpiperidine–dithiocarbamate) with an infinite one-dimensional structure was synthesized and structurally characterized using X-ray diffraction. The electronic properties of the coordination polymer were investigated by UV-vis-NIR spectroscopy. Impedance measurement results demonstrated that this complex has a narrow bandgap, inducing semiconducting behavior.
ISSN:1144-0546
1369-9261
DOI:10.1039/C7NJ04763K