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look inside of diamond-forming media in deep subduction zones
Geologists have "known" for many years that continental crust is buoyant and cannot be subducted very deep. Microdiamonds 10-80 μm in size discovered in the 1980s within metamorphic rocks related to continental collisions clearly refute this statement, suggesting that material of continent...
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Published in: | Proceedings of the National Academy of Sciences - PNAS 2007-05, Vol.104 (22), p.9128-9132 |
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description | Geologists have "known" for many years that continental crust is buoyant and cannot be subducted very deep. Microdiamonds 10-80 μm in size discovered in the 1980s within metamorphic rocks related to continental collisions clearly refute this statement, suggesting that material of continental crust has been subducted to a minimum depth of >150 km and incorporated into mountain chains during tectonic exhumation. Over the past decade, the rapidly moving technological advancement has made it possible to examine these diamonds in detail, and to learn that they contain nanometric multiphase inclusions of crystalline and fluid phases and are characterized by a "crustal" signature of carbon stable isotopes. Scanning and transmission electron microscopy, focused ion beam techniques, synchrotron infrared spectroscopy, and nano-secondary ion mass spectrometry studies of these diamonds provide evidence that they were crystallized from a supercritical carbon-oxygen-hydrogen fluid. These microdiamonds preserve evidence of the pathway by which carbon and water can be subducted to mantle depths and returned back to the earth's surface. |
doi_str_mv | 10.1073/pnas.0609161104 |
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II</creator><creatorcontrib>Dobrzhinetskaya, Larissa F ; Wirth, Richard ; Green, Harry W. II ; Brookhaven National Laboratory (BNL) National Synchrotron Light Source</creatorcontrib><description>Geologists have "known" for many years that continental crust is buoyant and cannot be subducted very deep. Microdiamonds 10-80 μm in size discovered in the 1980s within metamorphic rocks related to continental collisions clearly refute this statement, suggesting that material of continental crust has been subducted to a minimum depth of >150 km and incorporated into mountain chains during tectonic exhumation. Over the past decade, the rapidly moving technological advancement has made it possible to examine these diamonds in detail, and to learn that they contain nanometric multiphase inclusions of crystalline and fluid phases and are characterized by a "crustal" signature of carbon stable isotopes. Scanning and transmission electron microscopy, focused ion beam techniques, synchrotron infrared spectroscopy, and nano-secondary ion mass spectrometry studies of these diamonds provide evidence that they were crystallized from a supercritical carbon-oxygen-hydrogen fluid. These microdiamonds preserve evidence of the pathway by which carbon and water can be subducted to mantle depths and returned back to the earth's surface.</description><identifier>ISSN: 0027-8424</identifier><identifier>EISSN: 1091-6490</identifier><identifier>DOI: 10.1073/pnas.0609161104</identifier><identifier>PMID: 17389388</identifier><language>eng</language><publisher>United States: National Academy of Sciences</publisher><subject>08 HYDROGEN ; CARBON ; CONTINENTAL CRUST ; CRYSTALLIZATION ; Crystallography ; Crystals ; DIAMONDS ; Fluids ; Garnets ; Geology ; High-Pressure Geoscience Special Feature ; HYDROGEN ; Inclusions ; Infrared radiation ; ION BEAMS ; Mass spectrometry ; MASS SPECTROSCOPY ; METAMORPHIC ROCKS ; Mineralogy ; Minerals ; MOUNTAINS ; national synchrotron light source ; Nitrogen ; OXYGEN ; PARTICLE ACCELERATORS ; Petrology ; Physical Sciences ; Rocks ; Scanning electron microscopy ; SPECTROSCOPY ; STABLE ISOTOPES ; SUBDUCTION ZONES ; SYNCHROTRON RADIATION ; Synchrotrons ; TECTONICS ; TRANSMISSION ELECTRON MICROSCOPY ; WATER</subject><ispartof>Proceedings of the National Academy of Sciences - PNAS, 2007-05, Vol.104 (22), p.9128-9132</ispartof><rights>Copyright 2007 The National Academy of Sciences of the United States of America</rights><rights>Copyright National Academy of Sciences May 29, 2007</rights><rights>2007 by The National Academy of Sciences of the USA 2007</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a663t-66e48c6ba63f6bed2ead0801df750ea3ab3f7c4b0aeab8a4c7de83ed265416143</citedby><cites>FETCH-LOGICAL-a663t-66e48c6ba63f6bed2ead0801df750ea3ab3f7c4b0aeab8a4c7de83ed265416143</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://www.pnas.org/content/104/22.cover.gif</thumbnail><linktopdf>$$Uhttps://www.jstor.org/stable/pdf/25427817$$EPDF$$P50$$Gjstor$$H</linktopdf><linktohtml>$$Uhttps://www.jstor.org/stable/25427817$$EHTML$$P50$$Gjstor$$H</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793,58238,58471</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17389388$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/930440$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Dobrzhinetskaya, Larissa F</creatorcontrib><creatorcontrib>Wirth, Richard</creatorcontrib><creatorcontrib>Green, Harry W. II</creatorcontrib><creatorcontrib>Brookhaven National Laboratory (BNL) National Synchrotron Light Source</creatorcontrib><title>look inside of diamond-forming media in deep subduction zones</title><title>Proceedings of the National Academy of Sciences - PNAS</title><addtitle>Proc Natl Acad Sci U S A</addtitle><description>Geologists have "known" for many years that continental crust is buoyant and cannot be subducted very deep. Microdiamonds 10-80 μm in size discovered in the 1980s within metamorphic rocks related to continental collisions clearly refute this statement, suggesting that material of continental crust has been subducted to a minimum depth of >150 km and incorporated into mountain chains during tectonic exhumation. Over the past decade, the rapidly moving technological advancement has made it possible to examine these diamonds in detail, and to learn that they contain nanometric multiphase inclusions of crystalline and fluid phases and are characterized by a "crustal" signature of carbon stable isotopes. Scanning and transmission electron microscopy, focused ion beam techniques, synchrotron infrared spectroscopy, and nano-secondary ion mass spectrometry studies of these diamonds provide evidence that they were crystallized from a supercritical carbon-oxygen-hydrogen fluid. 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II</au><aucorp>Brookhaven National Laboratory (BNL) National Synchrotron Light Source</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>look inside of diamond-forming media in deep subduction zones</atitle><jtitle>Proceedings of the National Academy of Sciences - PNAS</jtitle><addtitle>Proc Natl Acad Sci U S A</addtitle><date>2007-05-29</date><risdate>2007</risdate><volume>104</volume><issue>22</issue><spage>9128</spage><epage>9132</epage><pages>9128-9132</pages><issn>0027-8424</issn><eissn>1091-6490</eissn><abstract>Geologists have "known" for many years that continental crust is buoyant and cannot be subducted very deep. Microdiamonds 10-80 μm in size discovered in the 1980s within metamorphic rocks related to continental collisions clearly refute this statement, suggesting that material of continental crust has been subducted to a minimum depth of >150 km and incorporated into mountain chains during tectonic exhumation. Over the past decade, the rapidly moving technological advancement has made it possible to examine these diamonds in detail, and to learn that they contain nanometric multiphase inclusions of crystalline and fluid phases and are characterized by a "crustal" signature of carbon stable isotopes. Scanning and transmission electron microscopy, focused ion beam techniques, synchrotron infrared spectroscopy, and nano-secondary ion mass spectrometry studies of these diamonds provide evidence that they were crystallized from a supercritical carbon-oxygen-hydrogen fluid. These microdiamonds preserve evidence of the pathway by which carbon and water can be subducted to mantle depths and returned back to the earth's surface.</abstract><cop>United States</cop><pub>National Academy of Sciences</pub><pmid>17389388</pmid><doi>10.1073/pnas.0609161104</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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subjects | 08 HYDROGEN CARBON CONTINENTAL CRUST CRYSTALLIZATION Crystallography Crystals DIAMONDS Fluids Garnets Geology High-Pressure Geoscience Special Feature HYDROGEN Inclusions Infrared radiation ION BEAMS Mass spectrometry MASS SPECTROSCOPY METAMORPHIC ROCKS Mineralogy Minerals MOUNTAINS national synchrotron light source Nitrogen OXYGEN PARTICLE ACCELERATORS Petrology Physical Sciences Rocks Scanning electron microscopy SPECTROSCOPY STABLE ISOTOPES SUBDUCTION ZONES SYNCHROTRON RADIATION Synchrotrons TECTONICS TRANSMISSION ELECTRON MICROSCOPY WATER |
title | look inside of diamond-forming media in deep subduction zones |
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