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Mixed-Ligand Complexation of Zinc and Cobalt(II) Complexonates with Amino Acids in an Aqueous Solution
The formation of mixed-ligand complexes in the M(II)–Nta and Ida–L systems (M = Co, Zn; L = His, Orn, Lys, Gly, Im, en), where Ida and Nta are the residues of iminodiacetic and nitrilotriacetic acids, was studied by pH-metry, calorimetry, and NMR spectroscopy. The thermodynamic parameters (log K , Δ...
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| Published in: | Russian journal of inorganic chemistry 2018-02, Vol.63 (2), p.180-190 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c316t-26588927ad2d7ae2f72397752367a66cf60478d25b1913545c99f25b3d290c103 |
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| cites | cdi_FETCH-LOGICAL-c316t-26588927ad2d7ae2f72397752367a66cf60478d25b1913545c99f25b3d290c103 |
| container_end_page | 190 |
| container_issue | 2 |
| container_start_page | 180 |
| container_title | Russian journal of inorganic chemistry |
| container_volume | 63 |
| creator | Pyreu, D. F. Alekseeva, E. S. Simagina, T. A. Gruzdev, M. S. Kumeev, R. S. Gridchin, S. N. |
| description | The formation of mixed-ligand complexes in the M(II)–Nta and Ida–L systems (M = Co, Zn; L = His, Orn, Lys, Gly, Im, en), where Ida and Nta are the residues of iminodiacetic and nitrilotriacetic acids, was studied by pH-metry, calorimetry, and NMR spectroscopy. The thermodynamic parameters (log
K
, Δ
r
G
0
, Δ
r
H
, Δ
r
S
) of formation for these complexes were determined at 298.15 K and an ionic strength I = 0.5 (KNO3). The most probable pattern of coordination between a complexone and an amino acid in mixed-ligand complexes was revealed. |
| doi_str_mv | 10.1134/S0036023618020183 |
| format | article |
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K
, Δ
r
G
0
, Δ
r
H
, Δ
r
S
) of formation for these complexes were determined at 298.15 K and an ionic strength I = 0.5 (KNO3). The most probable pattern of coordination between a complexone and an amino acid in mixed-ligand complexes was revealed.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023618020183</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Amino acids ; Chemistry ; Chemistry and Materials Science ; Coordination Compounds ; Inorganic Chemistry ; Ligands ; NMR ; NMR spectroscopy ; Nuclear magnetic resonance ; Zinc</subject><ispartof>Russian journal of inorganic chemistry, 2018-02, Vol.63 (2), p.180-190</ispartof><rights>Pleiades Publishing, Ltd. 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-26588927ad2d7ae2f72397752367a66cf60478d25b1913545c99f25b3d290c103</citedby><cites>FETCH-LOGICAL-c316t-26588927ad2d7ae2f72397752367a66cf60478d25b1913545c99f25b3d290c103</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Pyreu, D. F.</creatorcontrib><creatorcontrib>Alekseeva, E. S.</creatorcontrib><creatorcontrib>Simagina, T. A.</creatorcontrib><creatorcontrib>Gruzdev, M. S.</creatorcontrib><creatorcontrib>Kumeev, R. S.</creatorcontrib><creatorcontrib>Gridchin, S. N.</creatorcontrib><title>Mixed-Ligand Complexation of Zinc and Cobalt(II) Complexonates with Amino Acids in an Aqueous Solution</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>The formation of mixed-ligand complexes in the M(II)–Nta and Ida–L systems (M = Co, Zn; L = His, Orn, Lys, Gly, Im, en), where Ida and Nta are the residues of iminodiacetic and nitrilotriacetic acids, was studied by pH-metry, calorimetry, and NMR spectroscopy. The thermodynamic parameters (log
K
, Δ
r
G
0
, Δ
r
H
, Δ
r
S
) of formation for these complexes were determined at 298.15 K and an ionic strength I = 0.5 (KNO3). The most probable pattern of coordination between a complexone and an amino acid in mixed-ligand complexes was revealed.</description><subject>Amino acids</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination Compounds</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>NMR</subject><subject>NMR spectroscopy</subject><subject>Nuclear magnetic resonance</subject><subject>Zinc</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kD9PwzAQxS0EEqXwAdgsscAQ8NmxnYxRxZ9KRQyFhSVyHae4Su0SJ6J8exwFxICYTqf3e-9OD6FzINcALL1ZEsIEoUxARiiBjB2gCXAGSSaAHaLJICeDfoxOQtgQkqZEZhNUP9q9qZKFXStX4Znf7hqzV531Dvsav1qn8SisVNNdzudXP4x3qjMBf9juDRdb6zwutK0Cti4acPHeG98HvPRNP4SdoqNaNcGcfc8perm7fZ49JIun-_msWCSagegSKniW5VSqilZSGVpLynIpefxbKiF0LUgqs4ryFeTAeMp1ntdxYxXNiQbCpuhizN21Pr4QunLj-9bFk2VshQHnaS4iBSOlWx9Ca-py19qtaj9LIOVQZ_mnzuihoydE1q1N-5v8v-kLvyN0Ng</recordid><startdate>20180201</startdate><enddate>20180201</enddate><creator>Pyreu, D. F.</creator><creator>Alekseeva, E. S.</creator><creator>Simagina, T. A.</creator><creator>Gruzdev, M. S.</creator><creator>Kumeev, R. S.</creator><creator>Gridchin, S. N.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20180201</creationdate><title>Mixed-Ligand Complexation of Zinc and Cobalt(II) Complexonates with Amino Acids in an Aqueous Solution</title><author>Pyreu, D. F. ; Alekseeva, E. S. ; Simagina, T. A. ; Gruzdev, M. S. ; Kumeev, R. S. ; Gridchin, S. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-26588927ad2d7ae2f72397752367a66cf60478d25b1913545c99f25b3d290c103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Amino acids</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination Compounds</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>NMR</topic><topic>NMR spectroscopy</topic><topic>Nuclear magnetic resonance</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pyreu, D. F.</creatorcontrib><creatorcontrib>Alekseeva, E. S.</creatorcontrib><creatorcontrib>Simagina, T. A.</creatorcontrib><creatorcontrib>Gruzdev, M. S.</creatorcontrib><creatorcontrib>Kumeev, R. S.</creatorcontrib><creatorcontrib>Gridchin, S. N.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pyreu, D. F.</au><au>Alekseeva, E. S.</au><au>Simagina, T. A.</au><au>Gruzdev, M. S.</au><au>Kumeev, R. S.</au><au>Gridchin, S. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mixed-Ligand Complexation of Zinc and Cobalt(II) Complexonates with Amino Acids in an Aqueous Solution</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2018-02-01</date><risdate>2018</risdate><volume>63</volume><issue>2</issue><spage>180</spage><epage>190</epage><pages>180-190</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>The formation of mixed-ligand complexes in the M(II)–Nta and Ida–L systems (M = Co, Zn; L = His, Orn, Lys, Gly, Im, en), where Ida and Nta are the residues of iminodiacetic and nitrilotriacetic acids, was studied by pH-metry, calorimetry, and NMR spectroscopy. The thermodynamic parameters (log
K
, Δ
r
G
0
, Δ
r
H
, Δ
r
S
) of formation for these complexes were determined at 298.15 K and an ionic strength I = 0.5 (KNO3). The most probable pattern of coordination between a complexone and an amino acid in mixed-ligand complexes was revealed.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023618020183</doi><tpages>11</tpages></addata></record> |
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| ispartof | Russian journal of inorganic chemistry, 2018-02, Vol.63 (2), p.180-190 |
| issn | 0036-0236 1531-8613 |
| language | eng |
| recordid | cdi_proquest_journals_2013155496 |
| source | Springer Nature |
| subjects | Amino acids Chemistry Chemistry and Materials Science Coordination Compounds Inorganic Chemistry Ligands NMR NMR spectroscopy Nuclear magnetic resonance Zinc |
| title | Mixed-Ligand Complexation of Zinc and Cobalt(II) Complexonates with Amino Acids in an Aqueous Solution |
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