Effect of the Nature of the Polymer Matrix on the Luminescence of Tb(III) Complexes with β-Diketone Copolymers

The formation conditions and luminescence of Tb(III) complexes with synthesized copolymers of unsaturated acetylacetone derivatives with styrene and methyl methacrylate were studied. The luminescence intensity of these Tb(III) complexes was found to depend on the β-diketone substituent nature (CH 3...

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Bibliographic Details
Published in:Russian journal of coordination chemistry 2018-03, Vol.44 (3), p.220-225
Main Authors: Meshkova, S. B., Shevchenko, O. V., Kovalenko, V. Yu, Doga, P. G., Gorodnyuk, V. P.
Format: Article
Language:English
Subjects:
Acetylacetone
Chemical synthesis
Chemistry
Chemistry and Materials Science
Copolymers
Inorganic Chemistry
Luminescence
Physical Chemistry
Polymethyl methacrylate
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Summary:The formation conditions and luminescence of Tb(III) complexes with synthesized copolymers of unsaturated acetylacetone derivatives with styrene and methyl methacrylate were studied. The luminescence intensity of these Tb(III) complexes was found to depend on the β-diketone substituent nature (CH 3 , CF 3 , C 6 H 5 ) and structure (linear, branched) and the β-diketone to monomer ratio in the polymerizing mixture.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328418020070