Structures of Bromoalkanes' Photodissociation in Solution by Means of Ultrafast Extended X-Ray Absorption Fine-Structure Spectroscopy

The structures of initial and final products of bromoalkanes' photodisociation reaction in cyclohexane solution have been measured with a bond length accuracy of 0.02 Å by means of ultrafast time-resolved extended x-ray absorption fine structure spectroscopy. The photoredaction mechanism is als...

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Bibliographic Details
Published in:Proceedings of the National Academy of Sciences - PNAS 2002-10, Vol.99 (20), p.12556-12561
Main Authors: Oulianov, D. A., Tomov, I. V., Dvornikov, A. S., Rentzepis, P. M.
Format: Article
Language:English
Subjects:
Atoms
Bromine
Chemical reactions
Coordination numbers
Experimental data
Fourier Analysis
Hydrocarbons, Brominated - chemistry
Irradiation
Lasers
Light
Liquids
Methods
Models, Chemical
Molecular structure
Molecules
Photolysis
Physical Sciences
Scattering, Radiation
Spectrometry, X-Ray Emission - methods
Spectrum analysis
Time Factors
Trihalomethanes - chemistry
Ultraviolet Rays
X-rays
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Summary:The structures of initial and final products of bromoalkanes' photodisociation reaction in cyclohexane solution have been measured with a bond length accuracy of 0.02 Å by means of ultrafast time-resolved extended x-ray absorption fine structure spectroscopy. The photoredaction mechanism is also discussed.
ISSN:0027-8424
1091-6490
DOI:10.1073/pnas.192447199