Crystal and Molecular Structure of a Platinum(II) Complex with β-Mercaptoethylamine Hydrochloride

The work describes in detail the structure of a coordination platinum(II) compound with the sulfur-and nitrogen-containing biologically active β-mercaptoethylamine ligand NH 2 CH 2 CH 2 SH which deprotonates during synthesis and acts simultaneously as a chelating and bridging ligand resulting in the...

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Bibliographic Details
Published in:Journal of structural chemistry 2018, Vol.59 (1), p.188-192
Main Authors: Azizova, A. N., Tagiev, D. B., Osmanova, S. N., Kasumov, Sh. G., Gasanov, Kh. I.
Format: Article
Language:English
Subjects:
Atomic
Atomic/Molecular Structure and Spectra
Chelation
Chemistry
Chemistry and Materials Science
Crystal structure
Inorganic Chemistry
Ligands
Molecular
Molecular structure
Optical and Plasma Physics
Physical Chemistry
Platinum
Solid State Physics
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Summary:The work describes in detail the structure of a coordination platinum(II) compound with the sulfur-and nitrogen-containing biologically active β-mercaptoethylamine ligand NH 2 CH 2 CH 2 SH which deprotonates during synthesis and acts simultaneously as a chelating and bridging ligand resulting in the formation of the hexanuclear [Pt 6 (NH 2 CH 2 CH 2 S) 8 ]Cl 4 ·3H 2 O complex of a non-cluster type. Depending on the conditions, in particular, medium pH, complexes with different nuclearities and hydration numbers can form in this system.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476618010298