Vine Shoots and Grape Stalks as Carbon Sources for Hydrogen Evolution Reaction Electrocatalyst Supports

Activated bio-based carbons produced from vine shoots (VSAC) and grape stalks (GSAC), which have larger surface area and total pore volume than most of the commercially available activated carbons, are used as supports for palladium nanoparticles (Pd NPs). The prepared materials are characterised by...

Full description

Saved in:
Bibliographic Details
Published in:Catalysts 2018-02, Vol.8 (2), p.50
Main Authors: Cardoso, J.A.S.B., Šljukić, B., Erdem, M., Sequeira, C.A.C., Santos, D.M.F.
Format: Article
Language:English
Subjects:
Activated carbon
Catalysts
Cathodic polarization
Chemical reactions
Electrocatalysts
Electron microscopy
Energy transmission
Hydrogen evolution reactions
Nanoparticles
Palladium
Scanning electron microscopy
Stability analysis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Activated bio-based carbons produced from vine shoots (VSAC) and grape stalks (GSAC), which have larger surface area and total pore volume than most of the commercially available activated carbons, are used as supports for palladium nanoparticles (Pd NPs). The prepared materials are characterised by elemental analysis, N2-sorption, X-ray diffraction, scanning electron microscopy with energy dispersive X-ray spectroscopy, and transmission electron microscopy analysis and are then assessed as potential cathodes for the hydrogen evolution reaction (HER) in alkaline media. The electrocatalysts’ performance for HER is evaluated from cathodic polarisation curves at different temperatures and compared to that of Vulcan XC72-supported Pd NPs. Additional chronoamperometry studies helped to assess the electrocatalysts’ activity stability. The novel VSAC-supported Pd electrocatalyst exhibits good HER activity in terms of high current density at low overpotentials, leading to the best performance.
ISSN:2073-4344
2073-4344
DOI:10.3390/catal8020050