Water Soluble Benzimidazole Containing Ionic Palladium(II) Complex for Rapid Microwave‐Assisted Suzuki Reaction of Aryl Chlorides

In this paper a water soluble benzimidazole – Pd complex used for Suzuki reaction under conventional heating and microwave heating. To increase the activity of complex, ionic group change with bulky TBA+ and Bmim+ groups. To determine whether the reaction is homogeneous or heterogeneous, Hg(0) poiso...

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Bibliographic Details
Published in:Applied organometallic chemistry 2018-04, Vol.32 (4), p.n/a
Main Authors: Şengül, Abdurrahman, Hanhan, Murat Emre
Format: Article
Language:English
Subjects:
Aromatic compounds
Benzimidazole
Chemical reactions
Chemistry
Green Chemistry
Heating
Microwave
Palladium
Palladium Complex
Poisoning
Suzuki Reaction
Water chemistry
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Summary:In this paper a water soluble benzimidazole – Pd complex used for Suzuki reaction under conventional heating and microwave heating. To increase the activity of complex, ionic group change with bulky TBA+ and Bmim+ groups. To determine whether the reaction is homogeneous or heterogeneous, Hg(0) poisoning tests, hot filtration tests and CS2 poisoning tests were performed. A new water soluble benzimidazole‐palladium(II) complex was synthesized and apllied on Suzuki reaction under microwave irradiation.
ISSN:0268-2605
1099-0739
DOI:10.1002/aoc.4288