Self-assembly on copper surface by using imidazole derivative for corrosion protection

This paper presents the self-assembly of 1-(3-aminopropyl) imidazole (API) monolayer on the copper surface to study the inhibition effect of the API against copper corrosion in 3% NaCl solution. The optimum concentration and assembling time for the assembly of API on copper were ascertained using el...

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Published in:Journal of adhesion science and technology 2018-08, Vol.32 (16), p.1733-1749
Main Authors: Durainatarajan, P., Prabakaran, M., Ramesh, S., Periasamy, V.
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Language:English
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description This paper presents the self-assembly of 1-(3-aminopropyl) imidazole (API) monolayer on the copper surface to study the inhibition effect of the API against copper corrosion in 3% NaCl solution. The optimum concentration and assembling time for the assembly of API on copper were ascertained using electrochemical impedance spectroscopy (EIS). It was found that the API self-assembled monolayer (SAM) was formed with the concentration of 1.0 mM of API at 24 h assembling time and the maximum inhibition efficiency that could be achieved was 93.10%. The API SAM on copper was characterized by Fourier transform infrared spectroscopy (FT-IR), energy dispersive X-ray analysis (EDX), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and water contact angle measurement (WCA). The presence of N and C signals in the XPS and EDX, show that the API molecules successfully anchor on the copper surface which demonstrates formation of API SAM on the copper surface. Corrosion protection capability of the copper modified with API was evaluated by the electrochemical polarization study (EPS) and scanning electron microscopy (SEM). The results of electrochemical and SEM analysis revealed that the API modified copper showed better corrosion protection in 3% NaCl solution.
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subjects Anchors
Assembling
Atomic beam spectroscopy
Atomic force microscopy
Contact angle
Copper
Corrosion
Corrosion effects
Corrosion prevention
Electrochemical impedance spectroscopy
Fourier transforms
Imidazole
Infrared analysis
Infrared spectroscopy
Monolayers
Scanning electron microscopy
Self-assembly
Sodium chloride
Spectrum analysis
X ray analysis
X ray photoelectron spectroscopy
title Self-assembly on copper surface by using imidazole derivative for corrosion protection
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