Reduced graphene oxide (rGO) as highly effective material for the ultrasound assisted boric acid extraction from ulexite ore

• Published in: Chemical engineering research & design 2017-01, Vol.117, p.542-548
• Main Authors: Gezer, Bahdişen, Sert, Hakan, Onal Okyay, Tuğba, Bozkurt, Sait, Başkaya, Gaye, Şahin, Birgütay, Ulutürk, Ceyda, Sen, Fatih
• Format: Article
• Language: English
• Subjects: Diffraction; Fourier transforms; Graphene; Gravimetry; Influence; Infrared analysis; Response surface methodology; rGO; Studies; Thermal analysis; Ulexite; Ultrasound assisted extraction; X-ray diffraction; Yield
• ISSN: 0263-8762; 1744-3563
• DOI: 10.1016/j.cherd.2016.11.007

[Display omitted] The extraction of boric acid from ulexite mineral was carried out for the first time using a new extraction method, ultrasonic-assisted extraction (UAE) method, within the response surface methodology (RSM). •Boric acid extraction was performed for the first time using ultrasound-assisted extraction with and without rGO.•Central composite design was used for optimizing the boric acid extraction.•The highest yield (91.41%) was obtained in literature.•Thanks to solvent/solid ratio, extraction time, temperature and pH for the extraction yield. In this study, an investigation of the optimum conditions to extract boric acid from ulexite mineral was examined for the first time to explore the boric acid extraction yield by employing a new extraction process, ultrasound-assisted extraction (UAE) by the help of reduced graphene oxide (rGO). Moreover, the influence of rGO has been investigated on the extraction of boric acid from ulexite mineral. Besides, the amount of extraction of boric acid from ulexite depends on reaction conditions. For this reason, the impacts of various solvent/solid ratio, pH, extraction time, and extraction temperature on the yield were investigated by the conductometric method. Experiments with rGO were carried out using one-factor-at-a-time methodology. Several experimental situations (with or without rGO) were used in order to compare the boric acid yield. It was explored that the amount of the boric acid extraction was increased importantly in the presence of rGO. Also, thermo-gravimetric assay (TG-DTA), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) analyses were utilized for the characterization of materials. Under optimum conditions, the yield was calculated as about 93–94% by the help of rGO, which is a greater value than the yields reported in the literature.