Reactions of Disubstituted Cyanamide Ligands in 3d-Metal Complexes

Structural features and reactivity of the N,N -disubstituted cyanamide ligands in the complexes of late 3 d metals are discussed. The results obtained by author’s research group within the recent four years are analyzed in comparison. The reactivity of the cyanamide and nitrile ligands in the presen...

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Bibliographic Details
Published in:Russian journal of coordination chemistry 2018-04, Vol.44 (4), p.227-242
Main Author: Bokach, N. A.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Coordination compounds
Cyanamides
Inorganic Chemistry
Ligands
Metals
Palladium
Physical Chemistry
Platinum
Transition metals
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Summary:Structural features and reactivity of the N,N -disubstituted cyanamide ligands in the complexes of late 3 d metals are discussed. The results obtained by author’s research group within the recent four years are analyzed in comparison. The reactivity of the cyanamide and nitrile ligands in the presence of the 3 d -metal salts is comparatively examined. The reaction behavior of substituted cyanamides in the presence of 3 d -metals is compared with that of coordinated cyanamides in the complexes of transition metals of the 4 d and 5 d series (platinum, palladium).
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328418040012