EDXRF analysis of suspended particulate matter (SPM) from residential and industrial areas in Cairo, Egypt

• Published in: X-ray spectrometry 2018-05, Vol.47 (3), p.223-230
• Main Authors: Shaltout, Abdallah A., Hassan, Salwa K., Karydas, Andreas G., Harfouche, Messaoud, Abd‐Elkader, Omar H., Kregsamer, Peter, Wobrauschek, Peter, Streli, Christina
• Format: Article
• Language: English
• Subjects: Air pollution; Aluminum; Anthropogenic factors; Copper; Detection limits; Dispersion; Environmental indicators; Fluorescence; Human influences; Industrial areas; Lead; Manganese; Nickel; Particulate emissions; Particulate matter; Pollutants; Residential areas; Selenium
• ISSN: 0049-8246; 1097-4539
• DOI: 10.1002/xrs.2830

Due to the remarkable increasing of the mass concentrations of suspended particulate matter (SPM) as an air pollution indicator in Greater Cairo‐Egypt, regular sampling during autumn 2014 and winter 2014/2015 seasons has been performed from industrial and residential areas. It was found that the average mass concentrations of the SPM collected from residential and industrial areas are equal to 531 ± 198 and 912 ± 230 μg/m3, respectively. These quantities are much higher than the maximum allowance level, especially for the industrial area. By utilizing three secondary targets, energy dispersive x‐ray fluorescence working under vacuum environment was used for elemental analysis of 19 elements namely; Na, Al, Si, S, Cl, K, Ca, Ti, V, Mn, Fe, Ni, Cu, Zn, Pb, Se, Br, Rb, and Sr. The present optimized selective excitation energy dispersive x‐ray fluorescence analysis has considerably enhanced the analytical range with respect to our previous similar studies, including low Z elements such as Na, Al, S, and Cl and attaining lower detection limits in the range of ng/m3. Remarkable high elemental concentrations were determined for most of the detected elements from the industrial area samples, strongly indicating the influence of the industrial and anthropogenic activities. The average percentages of the mass concentration of the detected inorganic elements account only for 3.2% and 10.5% of the total mass concentration collected from the residential and industrial areas, respectively, thus directly indicating that the content of organic pollutants in SPM is the dominant contribution.