Recent Progress of the Solid‐State Electrolytes for High‐Energy Metal‐Based Batteries

• Published in: Advanced energy materials 2018-04, Vol.8 (11), p.n/a
• Main Authors: Fan, Lei, Wei, Shuya, Li, Siyuan, Li, Qi, Lu, Yingying
• Format: Article
• Language: English
• Subjects: Aluminum; Anodes; Composite materials; dendrites; Electrolytes; Energy storage; high‐energy batteries; Interface reactions; Interface stability; Ion currents; metal anodes; Molten salt electrolytes; Polymer matrix composites; R&D; Research & development; solid electrolyte interphases; Solid electrolytes; solid‐state electrolytes; Storage batteries; Storage systems; Zinc
• ISSN: 1614-6832; 1614-6840
• DOI: 10.1002/aenm.201702657

Secondary batteries based on metal anodes (e.g., Li, Na, Mg, Zn, and Al) are among the most sought‐after candidates for next‐generation mobile and stationary storage systems because they are able to store a larger amount of energy per unit mass or volume. However, unstable electrodeposition and uncontrolled interfacial reactions occuring in liquid electrolytes cause unsatisfying cell performance and potential safety concerns for the commercial application of these metal anodes. Solid‐state electrolytes (SSEs) having a higher modulus are considered capable of inhibiting difficulties associated with the anodes and may enable building of safe all‐solid‐state metal batteries, yet several challenges, such as insufficient room‐temperature ionic conductivity and poor interfacial stability between the electrode and the electrolyte, hinder the large‐scale development of such batteries. Here, research and development of SSEs including inorganic ceramics, organic solid polymers, and organic–inorganic hybrid/composite materials for metal‐based batteries are reviewed. The comparison of different types of electrolytes is discussed in detail, in the context of electrochemical energy storage applications. Then, the focus of this study is on recent advances in a range of attractive and innovative battery chemistries and technologies that are enabled by SSEs. Finally, the challenges and future perspectives are outlined to foresee the development of SSEs. Recent progress of the solid‐state electrolytes (SSEs) for high‐energy metal‐based batteries and the current and potential innovative applications of SSE are reviewed. SSEs are classified into ceramic electrolytes, solid polymer electrolytes, and hybrid/composite electrolytes. The ion‐transport mechanism and their applications in different types of metal batteries are discussed. Finally, the design concepts of SSEs for specific battery applications are demonstrated.