Synthesis of Tricyclic Diesters from 8-Acetoxytricyclodec-3-ene Monoester

Tricyclic diesters were synthesized in yields of 70.4–90.8% by the addition of С 2 –С 5 monobasic carboxylic acids to tricyclo[5.2.1.0 2,6 ]dec-3-еn-8-yl acetate in the presence of a BF 3 ·OEt 2 catalyst. One of the synthesized diesters, tricyclodec-3,8-diyl diacetate, has a pleasant smell with a ci...

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Published in:Russian journal of general chemistry 2018-03, Vol.88 (3), p.393-396
Main Authors: Mamedov, M. K., Makhmudova, E. G., Rasulova, R. A., Abdullaeva, A. Dzh
Format: Article
Language:English
Subjects:
Acetic acid
Carboxylic acids
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Dicyclopentadiene
Diesters
Organic compounds
Smell
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container_issue 3
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container_title Russian journal of general chemistry
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creator Mamedov, M. K.
Makhmudova, E. G.
Rasulova, R. A.
Abdullaeva, A. Dzh
description Tricyclic diesters were synthesized in yields of 70.4–90.8% by the addition of С 2 –С 5 monobasic carboxylic acids to tricyclo[5.2.1.0 2,6 ]dec-3-еn-8-yl acetate in the presence of a BF 3 ·OEt 2 catalyst. One of the synthesized diesters, tricyclodec-3,8-diyl diacetate, has a pleasant smell with a citrus scent and can be used in different perfume compositions as a flavoring.
doi_str_mv 10.1134/S1070363218030039
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subjects Acetic acid
Carboxylic acids
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Dicyclopentadiene
Diesters
Organic compounds
Smell
title Synthesis of Tricyclic Diesters from 8-Acetoxytricyclodec-3-ene Monoester
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