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Enhanced wettability and thermal stability of polypropylene separators by organic–inorganic coating layer for lithium‐ion batteries
ABSTRACT Organic–inorganic coating polypropylene separators were developed by introducing SiO2 nanoparticles through sol–gel process, where polydopamine was used as an intermediate layer. Scanning electron microscopy results showed the coating layers have highly porous structure, which was beneficia...
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| Published in: | Journal of applied polymer science 2018-07, Vol.135 (28), p.n/a |
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| Main Authors: | , , , , , , |
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| cited_by | cdi_FETCH-LOGICAL-c3348-ac64632f471774f41bbdc4653f13537f47e929eeeaf7e249734921dc51e5901f3 |
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| cites | cdi_FETCH-LOGICAL-c3348-ac64632f471774f41bbdc4653f13537f47e929eeeaf7e249734921dc51e5901f3 |
| container_end_page | n/a |
| container_issue | 28 |
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| container_title | Journal of applied polymer science |
| container_volume | 135 |
| creator | Chao, Chun‐Ying Feng, Ye‐Fei Hua, Kai Li, Hao Wu, Li‐Jun Zhou, Yi‐Sha Dong, Zhen‐Wei |
| description | ABSTRACT
Organic–inorganic coating polypropylene separators were developed by introducing SiO2 nanoparticles through sol–gel process, where polydopamine was used as an intermediate layer. Scanning electron microscopy results showed the coating layers have highly porous structure, which was beneficial for liquid electrolyte uptake. Compared with pristine polypropylene separator, the ceramic separators showed improved thermal stability, higher ionic conductivity, and lower interfacial impedance. The cells employing the ceramic separators delivers excellent discharge capacity (retention = 75%) and coulombic efficiency up to 98% at 2 °C rate after 100 cycles. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46478. |
| doi_str_mv | 10.1002/app.46478 |
| format | article |
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Organic–inorganic coating polypropylene separators were developed by introducing SiO2 nanoparticles through sol–gel process, where polydopamine was used as an intermediate layer. Scanning electron microscopy results showed the coating layers have highly porous structure, which was beneficial for liquid electrolyte uptake. Compared with pristine polypropylene separator, the ceramic separators showed improved thermal stability, higher ionic conductivity, and lower interfacial impedance. The cells employing the ceramic separators delivers excellent discharge capacity (retention = 75%) and coulombic efficiency up to 98% at 2 °C rate after 100 cycles. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46478.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.46478</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc</publisher><subject>ceramic coating ; Electrolytic cells ; Inorganic coatings ; Interface stability ; Ion currents ; Lithium-ion batteries ; lithium‐ion battery ; Materials science ; Polymers ; Polypropylene ; Scanning electron microscopy ; separator ; Separators ; Silicon dioxide ; Sol-gel processes ; Thermal stability ; Wettability</subject><ispartof>Journal of applied polymer science, 2018-07, Vol.135 (28), p.n/a</ispartof><rights>2018 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3348-ac64632f471774f41bbdc4653f13537f47e929eeeaf7e249734921dc51e5901f3</citedby><cites>FETCH-LOGICAL-c3348-ac64632f471774f41bbdc4653f13537f47e929eeeaf7e249734921dc51e5901f3</cites><orcidid>0000-0001-5040-4044</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Chao, Chun‐Ying</creatorcontrib><creatorcontrib>Feng, Ye‐Fei</creatorcontrib><creatorcontrib>Hua, Kai</creatorcontrib><creatorcontrib>Li, Hao</creatorcontrib><creatorcontrib>Wu, Li‐Jun</creatorcontrib><creatorcontrib>Zhou, Yi‐Sha</creatorcontrib><creatorcontrib>Dong, Zhen‐Wei</creatorcontrib><title>Enhanced wettability and thermal stability of polypropylene separators by organic–inorganic coating layer for lithium‐ion batteries</title><title>Journal of applied polymer science</title><description>ABSTRACT
Organic–inorganic coating polypropylene separators were developed by introducing SiO2 nanoparticles through sol–gel process, where polydopamine was used as an intermediate layer. Scanning electron microscopy results showed the coating layers have highly porous structure, which was beneficial for liquid electrolyte uptake. Compared with pristine polypropylene separator, the ceramic separators showed improved thermal stability, higher ionic conductivity, and lower interfacial impedance. The cells employing the ceramic separators delivers excellent discharge capacity (retention = 75%) and coulombic efficiency up to 98% at 2 °C rate after 100 cycles. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46478.</description><subject>ceramic coating</subject><subject>Electrolytic cells</subject><subject>Inorganic coatings</subject><subject>Interface stability</subject><subject>Ion currents</subject><subject>Lithium-ion batteries</subject><subject>lithium‐ion battery</subject><subject>Materials science</subject><subject>Polymers</subject><subject>Polypropylene</subject><subject>Scanning electron microscopy</subject><subject>separator</subject><subject>Separators</subject><subject>Silicon dioxide</subject><subject>Sol-gel processes</subject><subject>Thermal stability</subject><subject>Wettability</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kL9OwzAQxi0EEqUw8AaWmBjS2rGT1GNVlT9SJTrAHDnpuXWV2sF2VWXrxorEG_ZJMLRiY7rTfb_7TvchdEvJgBKSDmXbDnjOi9EZ6lEiioTn6egc9aJGk5EQ2SW68n5NCKUZyXvoY2pW0tSwwDsIQVa60aHD0ixwWIHbyAb7v6lVuLVN1zrbdg0YwB5a6WSwzuMqym4pja4P-y9tTj2urQzaLHEjO3BYWYej00pvN4f9p7YGVzIEcBr8NbpQsvFwc6p99PYwfZ08JbOXx-fJeJbUjPFRIuuc5yxVvKBFwRWnVbWoeZ4xRVnGijgHkQoAkKqAlIuCcZHSRZ1RyAShivXR3dE3fvG-BR_Ktd06E0-WKUmjK2dCROr-SNXOeu9Ala3TG-m6kpLyJ-cy5lz-5hzZ4ZHd6Qa6_8FyPJ8fN74BDOCEKA</recordid><startdate>20180720</startdate><enddate>20180720</enddate><creator>Chao, Chun‐Ying</creator><creator>Feng, Ye‐Fei</creator><creator>Hua, Kai</creator><creator>Li, Hao</creator><creator>Wu, Li‐Jun</creator><creator>Zhou, Yi‐Sha</creator><creator>Dong, Zhen‐Wei</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-5040-4044</orcidid></search><sort><creationdate>20180720</creationdate><title>Enhanced wettability and thermal stability of polypropylene separators by organic–inorganic coating layer for lithium‐ion batteries</title><author>Chao, Chun‐Ying ; Feng, Ye‐Fei ; Hua, Kai ; Li, Hao ; Wu, Li‐Jun ; Zhou, Yi‐Sha ; Dong, Zhen‐Wei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3348-ac64632f471774f41bbdc4653f13537f47e929eeeaf7e249734921dc51e5901f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>ceramic coating</topic><topic>Electrolytic cells</topic><topic>Inorganic coatings</topic><topic>Interface stability</topic><topic>Ion currents</topic><topic>Lithium-ion batteries</topic><topic>lithium‐ion battery</topic><topic>Materials science</topic><topic>Polymers</topic><topic>Polypropylene</topic><topic>Scanning electron microscopy</topic><topic>separator</topic><topic>Separators</topic><topic>Silicon dioxide</topic><topic>Sol-gel processes</topic><topic>Thermal stability</topic><topic>Wettability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chao, Chun‐Ying</creatorcontrib><creatorcontrib>Feng, Ye‐Fei</creatorcontrib><creatorcontrib>Hua, Kai</creatorcontrib><creatorcontrib>Li, Hao</creatorcontrib><creatorcontrib>Wu, Li‐Jun</creatorcontrib><creatorcontrib>Zhou, Yi‐Sha</creatorcontrib><creatorcontrib>Dong, Zhen‐Wei</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chao, Chun‐Ying</au><au>Feng, Ye‐Fei</au><au>Hua, Kai</au><au>Li, Hao</au><au>Wu, Li‐Jun</au><au>Zhou, Yi‐Sha</au><au>Dong, Zhen‐Wei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced wettability and thermal stability of polypropylene separators by organic–inorganic coating layer for lithium‐ion batteries</atitle><jtitle>Journal of applied polymer science</jtitle><date>2018-07-20</date><risdate>2018</risdate><volume>135</volume><issue>28</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>ABSTRACT
Organic–inorganic coating polypropylene separators were developed by introducing SiO2 nanoparticles through sol–gel process, where polydopamine was used as an intermediate layer. Scanning electron microscopy results showed the coating layers have highly porous structure, which was beneficial for liquid electrolyte uptake. Compared with pristine polypropylene separator, the ceramic separators showed improved thermal stability, higher ionic conductivity, and lower interfacial impedance. The cells employing the ceramic separators delivers excellent discharge capacity (retention = 75%) and coulombic efficiency up to 98% at 2 °C rate after 100 cycles. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46478.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/app.46478</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-5040-4044</orcidid></addata></record> |
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| language | eng |
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| source | Wiley |
| subjects | ceramic coating Electrolytic cells Inorganic coatings Interface stability Ion currents Lithium-ion batteries lithium‐ion battery Materials science Polymers Polypropylene Scanning electron microscopy separator Separators Silicon dioxide Sol-gel processes Thermal stability Wettability |
| title | Enhanced wettability and thermal stability of polypropylene separators by organic–inorganic coating layer for lithium‐ion batteries |
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